Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Salicylate-Selective Electrodes Based on Tripodal Tris-thiourea Derivatives

  • Lee, Chaeg-Yeong (Department of Chemistry (BK21), Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Jung-Hwan (Department of Chemistry (BK21), Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Dong-Wan (Department of Chemistry (BK21), Research Institute of Natural Science, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry (BK21), Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Jin-Eun (Department of Chemistry (BK21), Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Jae-Sang (Department of Chemistry (BK21), Research Institute of Natural Science, Gyeongsang National University)
  • Published : 2007.12.20
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Abstract

A new highly salicylate-selective PVC membrane electrode based on tripodal tris-thiourea derivatives, L1 and L2, as neutral carriers is described. The electrodes display an excellent potentiometric response to salicylate ions and an anti-Hofmeister selectivity sequence in the following order: Salicylate? > ClO4 ? > Benzoate? > I? >NO3? > NO2? > Maleate? > Acetate? > Lactate? > Fumarate?. It also exhibited a near-Nernstian potential in a linear range of 5.0 × 10?5 - 1.0 × 10?1 M with a detection limit of 9.0 × 10?5 mol/L and a slope of ?59.9 mV/decade at a pH of 7.0 in a saline buffer solution at 25 oC. The stability constant (log KS) of the anionsionophore complex was also determined at 25 oC by a conductometric titration in DMSO solution.

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