Bulletin of the Korean Chemical Society

  • 제28권2호
  • /
  • Pages.281-284
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  • 2007
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Nickel-Catalyzed Hydrogenolysis of Arenesulfonates Using Secondary Alkyl Grignard Reagents

  • Kim, Chul-Bae (School of Chemical & Materials Engineering, Chung-Ang University) ;
  • Cho, Chul-Hee (School of Chemical & Materials Engineering, Chung-Ang University) ;
  • Park, Kwang-Yong (School of Chemical & Materials Engineering, Chung-Ang University)
  • 발행 : 2007.02.20
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⟨ 이전 논문 다음 논문 ⟩

초록

Neopentyl arenesulfonates react with secondary alkylmagnesium chlorides in the presence of dppfNiCl2 to produce the corresponding arenes via the reductive cleavage of carbon-sulfur bond. Highest yield is obtained by using three equivalents of Grignard reagent to a mixture of arenesulfonate and dppfNiCl2 in Et2O at room temperature. This reaction represents a novel method allowing the efficient hydrogenolysis of sulfur-containing groups in aromatic compounds.

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참고문헌

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