Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Solvent Effect on Sulfur Ylide Mediated Epoxidation Reaction

  • Lee, Hee-Yoon (Center for Molecular Design and Synthesis, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology) ;
  • Bae, Im-Hyuck (Center for Molecular Design and Synthesis, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology) ;
  • Min, Kyung-Hyun (Center for Molecular Design and Synthesis, Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology)
  • Published : 2007.11.20
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Abstract

The solvent effect on sulfur ylide mediated epoxidation reaction was studied systematically. While higher trans/cis ratio of the epoxide was obtained in the more polar solvent, protic solvent produced the lower trans/ cis ratio than any aprotic solvent.

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References

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