Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl5

  • Georgea, Soney C. (Department of Chemistry, Inha University) ;
  • Kim, Sung-Soo (Department of Chemistry, Inha University)
  • Published : 2007.07.20
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Abstract

A simple and convenient method for the addition of TMSCN to carbonyl compounds is described. NbCl5 is found to possess a strong Lewis acid property to transform carbonyl compounds smoothly to the corresponding cyanosilylether in high yields (up to 99 %) in solvent- free conditions.

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References

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