Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Efficient Blue Light Emitting Diode by Using Anthracene Derivative with 3,5-Diphenylphenyl Wings at 9- and 10-Position

  • Kim, Yun-Hi (Department of Chemistry, Gyeongsang National University) ;
  • Lee, Sung-Joong (Department of Chemistry & Research Institute of Life Science, Gyeongsang National University) ;
  • Jung, Sang-Yun (SKC) ;
  • Byeon, Ki-Nam (SKC) ;
  • Kim, Jeong-Sik (School of Nano & Advanced Materials and Engineering Research Institute, Gyeongsang National University) ;
  • Shin, Sung-Chul (Department of Chemistry & Research Institute of Life Science, Gyeongsang National University) ;
  • Kwon, Soon-Ki (School of Nano & Advanced Materials and Engineering Research Institute, Gyeongsang National University)
  • Published : 2007.03.20
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Abstract

The novel blue light emitting material, 9,10-bis(3',5'-diphenylphenyl)anthracene (BDA) was synthesized by Suzuki coupling reaction and characterized by the measurements of 1H NMR, 13C NMR and FT-IR. The new anthracene derivative, which contains anthracene as a main core unit and 3',5'-diphenylphenyl group derivative as wings, has high fluorescence yield, good thermal stability, and high glass transition temperature at 188 oC. With the newly non-doped blue emitting material in the multilayer device structure, it was possible to achieve the current efficiency of 3.0 cd/A. The EL spectrum of the ITO/CuPc/α-NPD/BDA/Alq3/LiF/Al device showed a maximum wavelength (λmax) at 440 nm. The emitting color of device showed the blue emission (x,y) = (0.18,0.19) at 10 mA/cm2 in CIE (Commission Internationale de l'Eclairage) chromaticity coordinates.

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References

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