Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Ultrafast Time-Resolved Laser Spectroscopic Studies of trans-Bis(ferrocene-carboxylato)(tetraphenyl-porphyrinato)tin(IV): Intramolecular Electron-Transfer Dynamics

  • Jang, Joon-Hee (Department of Chemistry, Chungnam National University) ;
  • Kim, Hee-Jung (Department of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Kim, Hee-Joon (Department of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Kim, Chul-Hoon (Department of Chemistry, Pohang University of Science and Technology) ;
  • Joo, Tai-Ha (Department of Chemistry, Pohang University of Science and Technology) ;
  • Cho, Dae-Won (Department of Chemistry, Chosun University) ;
  • Yoon, Min-Joong (Department of Chemistry, Chungnam National University)
  • Published : 2007.11.20
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Abstract

Photophysical properties of a newly-synthesized porphyrin derivative, trans-bis(ferrocene carboxylato)- (5,10,15,20-tetraphenylporphyrinato)tin(IV) [Sn(TPP)(FcCOO)2] were investigated by means of steady-state and fs-time resolved laser spectroscopic techniques, and compared with those of a standard molecule, trans-dichloro( 5,10,15,20-tetraphenyl-porphrinato)tin(IV) [Sn(TPP)Cl2]. The fluorescence spectrum of Sn(TPP)- (FcCOO)2 was observed to exhibit dual emission bands originating from the S2-state and the S1-state, which was greatly quenched as compared to those of Sn(TPP)Cl2. The fs-time resolved fluorescence and transient absorption spectroscopic measurements revealed that the fluorescence quenching is due to formation of the long-lived charge transfer state by intramolecular electron transfer from ferrocene to the S2-excited SnTPP in addition to the enhanced non-radiative deactivation processes.

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References

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