Bulletin of the Korean Chemical Society

  • 제28권12호
  • /
  • Pages.2431-2434
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  • 2007
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Cyanosilylation of Carbonyl Compounds Catalyzed by Potassium L-Aspartate

  • George, Soney C. (Department of Chemistry, Inha University) ;
  • Kim, Sung-Soo (Department of Chemistry, Inha University) ;
  • Kim, Ho-Sub (Department of Chemistry, Inha University)
  • 발행 : 2007.12.20
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초록

Potassium L-aspartate has been used as a catalyst for the cyanosilylation of carbonyl compounds producing corresponding cyanohydrin trimethylsilyl ethers in excellent yield of up to 98%. Although the catalyst is chiral, the enantioselectivities observed are generally poor except for one case, α-naphthaldehyde, 89% ee.

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참고문헌

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피인용 문헌

  1. ChemInform Abstract: Cyanosilylation of Carbonyl Compounds Catalyzed by Potassium L-Aspartate. vol.39, pp.19, 2008, https://doi.org/10.1002/chin.200819044
  2. Regioselective Arylations of α-Amido Sulfones with Electron-Rich Arenes through Friedel-Crafts Alkylations Catalyzed by Ferric Chloride Hexahydrate: Synthesis of Unsymmetrical and Bis-Symmetrical Triarylmethanes vol.2010, pp.9, 2010, https://doi.org/10.1002/ejoc.200901186
  3. Fe(ClO4)3·×H2O-Catalyzed direct C–C bond forming reactions between secondary benzylic alcohols with different types of nucleophiles vol.66, pp.16, 2007, https://doi.org/10.1016/j.tet.2010.02.063
  4. Recent Progress in the Chemically Catalyzed Enantioselective Synthesis of Cyanohydrins vol.2010, pp.25, 2007, https://doi.org/10.1002/ejoc.201000462