Bulletin of the Korean Chemical Society

  • 제28권3호
  • /
  • Pages.451-456
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  • 2007
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Separation of Lithium Isotopes by Tetraazamacrocycles Tethered to Merrifield Peptide Resin

  • Jeon, Youn-Seok (Department of Chemistry Education, Kongju National University) ;
  • Jang, Nak-Han (Department of Science Education, Kongju National University of Education) ;
  • Kang, Byung-Moo (Department of Chemistry Education, Kongju National University) ;
  • Jeon, Young-Shin (Korea Atomic Energy Research Institute) ;
  • Kim, Chang-Suk (School of Science Education, Chungbuk National University) ;
  • Choi, Ki-Young (Department of Chemistry Education, Kongju National University) ;
  • Ryu, Hai-Il (Department of Chemistry Education, Kongju National University)
  • 발행 : 2007.03.20
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초록

Tetraazamacrocyclic ion exchangers tethered to Merrifield peptide resin (DTDM, TTTM) were prepared and the ion exchange capacity of these was characterized. The isotope separation of lithium was determined using breakthrough method of column chromatography. The isotope separation coefficient was strongly dependent on the ligand structure by Glueckauf's theory. We found that the isotope separation coefficients were increased as the values of distribution coefficients were increased. In this experiment the lighter isotope, 6Li was enriched in the resin phase, while the heavier isotope, 7Li in the solution phase. The ion radius of lighter isotope, 6Li was shorter than the heavier isotope, 7Li. The hydration number of lithium ion with the same charge became small as mass number was decreased. Because 6Li was more strongly retained in the resin than 7Li, the isotopes of lithium were separated with subsequent enrichment in the resin phase.

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참고문헌

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피인용 문헌

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  2. -4′-aminobenzo-15-crown-5-ether for Lithium Isotope Separation vol.54, pp.13, 2015, https://doi.org/10.1021/acs.iecr.5b00314
  3. Polyvinyl alcohol-graft-benzo-15-crown-5 ether for lithium isotopes separation by liquid–solid extraction vol.311, pp.3, 2017, https://doi.org/10.1007/s10967-017-5181-6
  4. 테트라아자 거대고리화합물(TDM, TPM)을 이용한 마그네슘동위원소의 분리에 관한 연구 vol.12, pp.10, 2011, https://doi.org/10.5762/kais.2011.12.10.4696