DOI QR코드

DOI QR Code

Influence of Sintering Temperature on Electrical and Dielectric Characteristics of Zn-Pr-Co-Cr-La Oxide-Based Nonlinear Resistors

Zn-Pr-Co-Cr-La 산화물계 비선형 저항체의 전기적, 유전적 성질에 소결온도가 미치는 영향

  • Nahm, Choon-Woo (Department of Electrical Engineering, Dongeui University)
  • 남춘우 (동의대학교 전기공학과)
  • Published : 2006.09.01

Abstract

The electrical and dielectric properties of $ZnO-Pr_6O_{11}CoO-Cr_2O_3La_2O_3-based$ nonlinear resistors were investigated at different sintering temperatures in the range of $1230{\sim}1300^{|circ}C$. As the sintering temperature increased, the breakdown voltage decreased from 777.9 to 108.0V/mm, the nonlinear coefficient greatly decreased from 77.0 to 7.1, and the leakage current increased from $0.4{\mu}A\;to\;50.6{\mu}A$. On the other hand, the donor density from $0.90{\times}10^{18}\;to\;2.59{\times}10^{18}/cm^3$ and the barrier height decreased from 1.89 to 0.69 eV with increasing temperature. The dielectric dissipation factor increased from 0.0879 to 0.2839 for the increase of sintering temperature.

Keywords

References

  1. L. M. Levinson and H. R. Pilipp, 'Zinc Oxide Varistor-A Review,' Am. Ceram. Soc. Bull., 65 [4] 639-46 (1986)
  2. T. K. Gupta, 'Application of Zinc Oxide Varistor,' J. Am. Ceram. Soc., 73 [7] 1817-40 (1990) https://doi.org/10.1111/j.1151-2916.1990.tb05232.x
  3. D. R. Clarke, 'Varistors Ceramics,' J. Am. Ceram. Soc., 82 [3] 485-502 (1999) https://doi.org/10.1111/j.1151-2916.1999.tb01793.x
  4. K. Mukae, K. Tsuda, and S. Shiga, 'Zinc Oxide-Praseodymium Oxide Elements for Surge Arresters,' IEEE Trans. Pow. Deliv., 3 [2] 591-98 (1988) https://doi.org/10.1109/61.4296
  5. S. Shichimiya, M. Yamaguchi, N. Furuse, M. Kobayashi, and S. Ishibe, 'Development of Advanced Arresters for GIS with New Zinc-Oxide Elements,' IEEE Trans. Pow. Deliv., 13 [2] 465-71 (1998) https://doi.org/10.1109/61.660916
  6. H. H. Hng and K. M. Knowles, 'Microstructure and Current- Voltage Characteristic of Praseodymium-Doped Zinc Oxide Varistors Containing $MnO_2,\;Sb_2O_3,\;and\;Co_3O_4$,' J. Mater. Sci., 37 [6] 1143-54 (2002) https://doi.org/10.1023/A:1014359204034
  7. C.-W. Nahm, $ZnO-Pr_6O_{11}-CoO-Cr_2O_3-Er_2O_3$ Based-Ceramic Varistors with High Stability of Nonlinear Properties,' J. Mater. Sci. Lett., 21 [3] 201-04 (2002) https://doi.org/10.1023/A:1014752523252
  8. C.-W. Nahm and H.-S. Kim, 'Influence of Cooling Rate on Stability of Nonlinear Properties of $ZnO-Pr_6O_{11}$-Based Varistor Ceramics,' Mater. Lett., 57 [9-10] 1544-49 (2003) https://doi.org/10.1016/S0167-577X(02)01020-0
  9. C.-W. Nahm, 'Microstructure and Electrical Properties of $Y_2O_3\;Doped\;ZnO-Pr_6O_{11}$-Based Varistor,' Mater. Lett., 57 [7] 1317-21 (2003) https://doi.org/10.1016/S0167-577X(02)00979-5
  10. C.-W. Nahm and B.-C. Shin, 'Effect of Sintering Time on Electrical Properties and Stability against DC Accelerated Aging of $Y_2O_3-Doped\;ZnO-Pr_6O_{11}$-Based Varistor Ceramics,' Ceram. Internation, 30 [1] 9-15 (2004) https://doi.org/10.1016/S0272-8842(03)00055-5
  11. C.-W. Nahm and B.-C. Shin, 'Effect of Sintering Time on Electrical Characteristics and DC Accelerated Aging Behaviors of Zn-Pr-Co-Cr-Dy Oxide-Based Varistors,' J. Mater. Sci.: Mater. Electron., 16 [11-12] 725-32 (2005) https://doi.org/10.1007/s10854-005-4975-4
  12. C.-W. Nahm, 'Influence of Cobalt Oxide Addition on Non- Linear Properties of $ZnO-Pr_6O_{11}$-Based Varistor Ceramics,' J. Mater. Sci., 40 [5] 1265-67 (2005) https://doi.org/10.1007/s10853-005-6948-7
  13. J. C. Wurst and J. A. Nelson, 'Lineal Intercept Technique for Measuring Grain Size in Two-Phase Polycrystalline Ceramics,' J. Am. Ceram. Soc., 97 [12] 109-11 (1972)
  14. K. Mukae, K. Tsuda, and I. Nagasawa, 'Capacitance-vs- Voltage Characteristics of ZnO Varistors,' J. Appl. Phys., 50 [6] 4475-76 (1979) https://doi.org/10.1063/1.326411
  15. L. Hozer, 'Semiconductor Ceramics; Grain Boundary Effects,' Ellis Horwood, 22 (1994)