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Fabrication of oxide buffer layers for coated conductors

MOD 공정에 의한 산화물 완충층 제조

  • 김영국 (한국기계연구원 신기능재료연구본부) ;
  • 유재무 (한국기계연구원 신기능재료연구본부) ;
  • 고재웅 (한국기계연구원 신기능재료연구본부) ;
  • 정국채 (한국기계연구원 신기능재료연구본부)
  • Published : 2006.09.01

Abstract

Oxide buffer layers for YBCO coated conductors were fabricated using MOD processing and development of microstructure and texture were investigated. A $CeO_2$ buffer layers were formed on RABiTS tape. Acetate-based precursor solution was employed to synthesize the precursor solution. Subsequently, the precursor solution was stabilized and modified with triethanolamine. $CeO_2$ precursor gel film was coated and annealed in $Ar/H_2$ atmosphere at high temperature. An annealed $CeO_2$ film shows mixed orientation with high (001) texturing. It was shown that (111) texture of $CeO_2$ layers were enhanced by multiple coating. This degradation was attributed to development of microcracks in the multiply coated $CeO_2$ films. Also discussed are the synthesis and the characterization of $La_2Zr_2O_7$ (LZO) buffer layers on RABiTS tape. A biaxially textured LZO buffer layer was fabricated with MOD processing method using metal alkoxide based precursor solution. It was shown that the LZO film were epitaxially grown on RABiTS tape and crack-free & uniform surface was obtained after annealing in $Ar/H_2$ atmosphere.

Keywords

References

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