AISI 420 stainless steel 기판위에 D.C magnetron sputtering 법으로 제조한 TiN 박막의 특성 평가

Processing and Characterization of RF Magnetron Sputtered TiN Films on AISI 420 Stainless Steel

  • 송승우 (전남대학교 공과대학 금속공학과) ;
  • 최한철 (조선대학교 치과대학 치의학과) ;
  • 김영만 (전남대학교 공과대학 금속공학과)
  • Song, Seung-Woo (Department of Materials Science and Engineering, Chonnam National University) ;
  • Choe, Han-Cheol (Department of Dental Materials, Chosun University) ;
  • Kim, Young-Man (Department of Materials Science and Engineering, Chonnam National University)
  • 발행 : 2006.10.30

초록

Titanium nitride (TiN) coatings were produced on AISI 420 stainless steel by DC magnetron sputtering of a Ti target changing the processing variables, such as the flow rate of $N_2/Ar$, substrate temperature and the existence of Ti interlayer between TiN coatings and substrates. The hardness and residual stress in the films were investigated using nanoindentation and a laser scanning device, respectively. The stoichiometry and surface morphology were investigated using X-Ray Diffraction and SEM. The corrosion property of the films was also studied using a polarization method in NaCl (0.9%) solution. Mechanical properties including hardness and residual stress were related to the ratio of $N_2/Ar$ flow rate. The corrosion resistance also was related to the processing variables.

키워드

참고문헌

  1. L. Hultman, Vacuum 57 (2000) 1 https://doi.org/10.1016/S0042-207X(00)00143-3
  2. R. Huhler, Cozza, T. L. Marcondcs. R. B. Souza, F. F. Fiori, Surface and Coatings Technology, 142-144 (2001) 164
  3. J. H. Je, E. Gyarmati, A. Naoumidis, Thin Solid Films, 136 (1986) 57 https://doi.org/10.1016/0040-6090(86)90108-2
  4. M. Y. Al-Jaroudi. H. T. G. Hentzell, S. E. Hornstrom, A. Bengslon. Thin Solid Films, 190 (1990) 265 https://doi.org/10.1016/0040-6090(89)90916-4
  5. W. J. Chou, G. P. Yu, J. H. Huang, Corrosion Science, 43 (2001) 2023 https://doi.org/10.1016/S0010-938X(01)00010-5
  6. W. Li, X. He, H. Li, J. Appl. Phys., 75 (1994) 2002
  7. J. W. Nah, B. J. Kim, D. K. Lee, J. J. Lee, J. Kor. Inst. Met. & Mater., 36(12) (1998)
  8. K. S. Mogensen, N. B. Thomsen, C. Mathiasen, J. Bolliger, Surface and Coatings Technology, 99 (1998) 140 https://doi.org/10.1016/S0257-8972(97)00420-9
  9. S. V. Fortuna, Y. P. Sharkeev, A . J. Perry, J. N. Matossian, I. A. Shulepov, Thin Solid Films, 377-378 (2000) 512
  10. C. B. In, B. J. Jung, W. J. Lee, S. S. Chun, Journal of the Korean Ceramic Society, 31(7) (1994) 731-738
  11. J. E. Sundgren, B. O. Johansson, S. E. Karlsson, H. T. G. Hentzell, Thin Solid Films, 105 (1983) 367 https://doi.org/10.1016/0040-6090(83)90319-X
  12. J. A. Thornton, J. Vac. Sci. Technol., 11 (1974) 666 https://doi.org/10.1116/1.1312732
  13. C. C. Jiang, T. Goto, T. Hirai, J. Mater. Sci., 28 (1993) 6446 https://doi.org/10.1007/BF01352211
  14. M. J. Buiting, A. F. Otterloo, A. H. Montree, J. Electrochem. Soc., 138 (1991) 500 https://doi.org/10.1149/1.2085618
  15. M. Herranen, U. Wiklund, J. O. Carlsson, Surface and Coatings Technology, 98 (1998) 191
  16. T. Okamoto, M. Fukushima, K. Takizawa, Corrosion Eng., 45 (1996) 425
  17. L. A. S. Ries, D. S. Azamhuja, I. J. R. Baumvol, Surface and Coatings Technology, 89 (1997) 114 https://doi.org/10.1016/S0257-8972(96)03092-7
  18. J. E. Sundgren, Thin Solid Films, 128 (1985) 21 https://doi.org/10.1016/0040-6090(85)90333-5
  19. G. M. Pharr, W. C. Oliver, MRS Bull., 17(7) (1992) 28
  20. V. Valvoda, Surface and Coatings Technology, 80 (1996) 61 https://doi.org/10.1016/0257-8972(95)02686-X
  21. J.-E. Sundgren, B.-O. Johansson, S.-E. Karlsson, H. T. G. Hentzell, Thin Solid Films, 105 (1983) 367 https://doi.org/10.1016/0040-6090(83)90319-X
  22. F. Elstner, A. Ehrlich, H. Giegengack, H. Kupfer, F. Richter, J. Vac. Sci. Technol A, 12 (1994) 476 https://doi.org/10.1116/1.579155
  23. G. Sloney. Royal Society of London Proc., A82 (1909) 172
  24. D. S. Rickerby, S . J. Bull, T. Robertsson, A. Henry, Surface and Coatings Technology, 41 (1990) 63 https://doi.org/10.1016/0257-8972(90)90130-5
  25. A . J. Perry, Thin Solid Films, 81 (1981) 357 https://doi.org/10.1016/0040-6090(81)90520-4
  26. B. K. Tay, X. Shi, H. S. Tan, D. Chua, S. Y. Teo : Surface and Coalings Technology, 111 (1999) 299
  27. J. A. Sue, Surface and Coatings Technology, 61 (1993) 115 https://doi.org/10.1016/0257-8972(93)90212-7
  28. A. Matthew, D. G. Teer, Thin Solid Films, 72 (1980) 541 https://doi.org/10.1016/0040-6090(80)90545-3
  29. A. Bendavid, P . J. Marlin, R. P. Neuerfield, T. J. Kinder, Surface and Coalings Technology, 70 (1994) 97 https://doi.org/10.1016/0257-8972(94)90080-9
  30. H. Uchida, S. Inoue, K. Koterazawa, Mater. Sci. Engng., A234-236 (1997) 649
  31. S. Inoue, H. Ucbida, K. Takeshita, K. Koterazawa, R. P. Howson, Thin Solid Film, 261 (1995) 115 https://doi.org/10.1016/S0040-6090(95)06527-X
  32. J. C. Francois, Y. Massiani, P. Gravier, J. Grirnbolt, J. Gengembre, Thin Solid Films 223 (1993) 223 https://doi.org/10.1016/0040-6090(93)90525-T
  33. M. Herranen, U. Wiklund, J.-O. Carlsson, S. Hogmark, Surface and Coalings Technology, 99 (1998)