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Selected spectral data of 3:
$^1H$ NMR (270 MHz;$CDCl_3$ , TMS)$\delta$ 1.82-2.12 (Ar-C$H_3$ ), 3.42-3.64 (-OC$H_3$ & -C$H_2$ Br), 3.81-3.95 (Ar-C$H_2$ -Ar), 4.16-4.21 (-OC$H_2$ -C$H_2$ -) -
Selected spectral data of 4:
$^1H$ NMR (270 MHz;$CDCl_3$ , TMS)$\delta$ 1.95-2.28 (Ar-C$H_3$ ), 2.02-2.23(C$H_3$ -C=O), 3.21-3.92 (-OC$H_3$ & -C$H_2$ & Ar-C$H_2$ -Ar & C$H_2$ -NC=O), FT-IR (KBr) 3400(N-H), 2940(-C$H_2$ -), 2850(OC$H_3$ ), 1620 (C=O), 1420 (Ar C=C), 1260 (Ph-O-C)$cm^{-1}$ - S. Kobayashi, M. Kaku, and T. Saegusa, Macromolecules, 21, 334 (1988) https://doi.org/10.1021/ma00180a009