Suppression of Solid Matters Precipitation of Takju and Its Quality Improvement by Carrageenan

Carrageenan에 의한 탁주 고형물 침전 억제 및 품질 개선에 관한 연구

  • Published : 2006.09.30

Abstract

This study was conducted to examine the possibility of improvement effect in suppression of precipitation and nasty smell creation in Takju mash. First of all, gum shown to be lowest precipitation velocity was selected and this was applied to the fermentation of Takju mash for comparing with the control in terms of fermentation aspects and various qualities of Takju mash. Precipitation amount and precipitation velocity of suspension in Takju mash added with carrageenan was shown to be the lowest than that of others. Compared with the control, alcohol was highly generated in Takju mash added with carrageenan, especially between two and four days. Total acidity was shown to be highly increased until 2 days in Takju mash and thereafter to be slightly increased. Takju mash added with carrageenan was shown to be lower on the second stage than the control. Fusel oil produced from mash added with carrageenan was 0.046${\sim}$0.113${\mu}$l/ml and mash added with carrageenan generated less fusel oil than the control by 1.6${\sim}$3.2 fold. Yeast growth on the mash added with carrageenan was revealed to be helpful during fermentation periods. In general, sensory characteristics of Takju mash were shown to be more superior in mash added with carrageenan than in other samples. While nasty smell produced from a sample without gums was perceived after 2 days of Takju mash storage, nasty smell of Takju mash added with carrageenan was recognized after 6 days during storage. In conclusion, precipitation of suspension and nasty smell production in Takju mash were found to be suppressed by addition of carrageenan during Takju fermentation.

본 연구는 탁주의 침전과 이취 발생 억제 등 품질개선을 위해 실시하였는데 고형물의 침전 속도가 가장 낮은 검류를 선택하여 이를 탁주 발효에 적용, 대조구와의 발효 양상 및 탁주의 품질을 서로 비교하였다. 우선 실험에 사용한 검류 중 carrageenan이 가장 좋은 효과를 나타내었는데 침전량이 가장 적고 침전 속도도 가장 느린 것으로 나타났다. 알코올 생성에 대해서는 carrageenan의 경우가 대조구보다 좋은 발효 양상을 보였으며 2${\sim}$4일 사이에 왕성하게 일어났다. 탁주의 산도는 2일째까지 산도가 많이 증가하고 그 이후에는 적게 증가하였으며 carrageenan의 경우 대조구보다 산도가 낮게 나타났다. 알코올 발효 과정의 fusel oil의 생성이 관해서는 carrageenan을 첨가한 경우(0.046${\sim}$0.113${\mu}$l/ml의 범위) 대조구보다 1.6배${\sim}$3.2배 낮게 나타났다. 효모 생육은 carrageenan을 첨가한 경우 효모 증식에 도움이 되는 것으로 나타났다. 탁주의 관능 평가에서는 carrageenan을 첨가한 것이 대조구보다 우수한 것으로 나타났다. 탁주의 저장 중 발생하는 이취(nasty smell)는 대조구는 저장 2일째부터, carrageenan을 첨가한 경우는 6일째부터 이취가 감지되었다. 결론적으로 탁주의 저장 중 침전과 이취의 발생 억제는 carrageenan을 첨가하므로 해결할 수 있을 것으로 생각되었다.

Keywords

References

  1. Lee, KB and Kim, JH. Studies on radiation preservation of fermented Korean rice-wine. Korean J. Microbial. 7:45-56. 1969
  2. Lee, J. Studies on the Qualities of Takju with Various Koji Strains. MS Thesis, Seoul Woman's Univ., Seoul. pp. 10-30. 1982
  3. Kim, CJ. Studies on the quantitative changes of organic acid and sugars during the fermentation of takju. Agricultural Chemistry & Biotechnology 4:33-42. 1963
  4. Lee, ZS and Rhee, TW. Studies on microflora of Takju brewing. Korean J. Microbiol. 8:116-133. 1970
  5. Cheung, JH. Studies on the identifcation of organic acids and sugars in the fermented mash of the Takju made from different raw materials. Agricultural Chemistry & Biotechnology 8:39-43. 1967
  6. Lee, WK, Kim, JR and Lee, MH. Studies on the changes in free amino acids and organic acids of Takju prepared with different koji strains. Agricultural Chemistry & Biotechnology 30:323-327. 1987
  7. Lee, TS and Han, EH. Volatile flavor components in mash of Takju prepared by using Rhizopus japonicus Nuruks. Korean J. Food Sci. Technol. 32:691-698. 2000
  8. Lee, TS and Choi, JY. Volatile flavor components in Takju fermented with mashed glutinous rice and barley rice. Korean J. Food Sci. Technol. 30:638-643. 1998
  9. Song, JC, Park, HJ and Shin, WC. Change of Takju qualities during the second brewing process by addition of alphaG-Hesperidine. J. Korean Soc. Food Sci. Nutr. 18:161-167, 2005
  10. Lee, SB, Chang, WG, Im, BJ and Kim, DC. Studies on chemical components of fermented mash in the brewing of Maggerley(Korean wine). Korean J. Microbiol. 7: 153-158. 1969
  11. Han, EH, Lee TS, Noh, BS and Lee, DS. Volatile flavor components in mash If Takju prepared by using different nuruks. Korean J. Food Sci. Technol. 29:563-570. 1997
  12. Lee, JS, Lee, TS, Park, SO and Noh, BS. Flavor components in mash of Takju prepared by different raw materials. Korean J. Food Sci. Technol. 28:316-323. 1996
  13. 배중호. 현미주의 제조방법. 대한민국 특허공개 특1984-0001214. 1984
  14. 서항원, 오평수, 권호정. 효소를 이용하여 무증자 전분으로부터 알코올을 제조하는 방법. 대한민국 특허공개 특1988-0002189. 1988
  15. 자연나라. www.jayeunnara.co.kr. 2005. 09.12 방문
  16. 임건우. 무증자 발효법에 의한 증류식 소주 및 약주의 제조 방법. 대한민국 특허공개 특2000-0028 347. 2000
  17. Song, JC, Park, HJ and Shin, WC. Changes of Takju Qulities by addition of cyclodextrin during the brewing and aging. Korean J. Food Sci. Technol. 29:895-900. 1997
  18. Rho, HJ, Park, CS, Kweon, MR, Moon, TW and Park, KH. Characteristics of amylose-lipid and cyclodextrin-lipid complex. J. Food Sci. Technol. 26:117-122. 1994
  19. Kim, HO and Hill, RD. Physical characteristics of wheat starch granule gelatinization in the presence of cycloheptaamylose. Cereal Chem. 61:432-438. 1984
  20. 越智敬志. Hydrocolloidcoの 食品工學への 應用. 食品工學 34(14):18-30.1991
  21. Whang, JK, Choe, MJ. Hydrocolloids and Food Rheology. Food Industry and Nutrition. 2: 41-50. 1997
  22. Song, JC, and Yang, HC. Food Additives. pp.394. Semoonsa. 1990
  23. National Tax Service Techical Service Institute. Alcoholic Liquors Analytical Rule : National Tax Service Instructions. 1267 National Tax Service Technical Service Institute. Seoul, Korea. 1999
  24. Song, JC and Park, HJ. Takju brewing using the uncooked germed brown rice at second stage mash. J. Korean Soc. Food Sci. Nutr. 32:847-854. 2003 https://doi.org/10.3746/jkfn.2003.32.6.847
  25. Kim, SK, Lee, AR, Lee, SK, Kim, KJ and Cheo, KC Firming rates of cooked rice differing in moisture contents. Korean J. Food Sci. Technol. 28:877-881. 1996
  26. Kum, JS, Lee, SH, Lee, HY and Lee, CH. Retrogradation behavior of rice starches differing in amylose content and gel consistency. Korean J. Food Sci. Technol. 28:1052-1058. 1996
  27. Mclver, RG, Axford, DWE, Colwell, KH and Elton, GAH. Kinetic study of the retrogradation of gelatinized starch. J. Sci. Food Agric. 19:560-565. 1968 https://doi.org/10.1002/jsfa.2740191003
  28. Piggot, JR Sensory Analysis of Foods. Elsevier Applied Science Publishers, London. 1984
  29. Song, JC and Park, HJ. Physical, Functional, Texture and Rheological properties of Foods. UUP, UOU. Ulsan. pp. 413-483. pp. 637-639. 2000
  30. 한정섭. 효소를 이용하여 무증자 전분으로부터 알코올을 제조하는 방법. 대한민국 특허공개 특1988-0002189. 1988
  31. 김종득. 생전분 당화 및 무증자 알콜발효방법. 대한민국 특허공개 96-1114. 1994
  32. 류근태, 박미연, 배정설, 조남철. 식품미생물학. pp. 241-250. 삼광출판사, 서울. 2002