The Characteristics of THMs Production by Different Disinfection Methods in Swimming Pools Water

수영장 욕조수의 소독방법에 따른 THMs 발생 특성

  • Lee Jin (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Ha Kwang-Tae (Seoul Metropolitan Government Research Institute of Public Health and Environment) ;
  • Zoh Kyung-Duk (Institute of Health & Environment, Seoul National University)
  • 이진 (서울시 보건환경연구원) ;
  • 하광태 (서울시 보건환경연구원) ;
  • 조경덕 (서울대학교 보건환경연구소)
  • Published : 2006.04.01

Abstract

The objectives of this study were to investigate the formation of trihalomethanes(THMs) and to compare the concentration level of THMs of swimming pools water by different disinfection methods such as chlorine, ozone-chlorine, and salt brine electrolysis generator (SBEG). The concentration of chloroform was the highest in the chlorine system, and the SBEG was the highest in the production of bromodichloromethane (BDCM), dibromochloromethane (DBCM) and bromoform. The average concentration of total trihalomethanes (TTHMs) in three disinfection systems were $64.5{\pm}27.4mg/l(SBEG),\;43.8{\pm}22.3mg/l(chlorine)$, and $30.6{\pm}16.1mg/l(ozone-chlorine)$, respectively. In chlorine and ozone-chlorine disinfection system, chloroform concentration was highest, followed by BDCN, then DBCM. In the SBEG, TTHMs was composed of 42% of chloroform, 28.9% of bromoform, 15.1% of BDCM and 14% of DBCM, respectively. The strongest correlation was obtained in the levels of chloroform and TTHMs in chlorine, and ozone-chlorine disinfection systems from both indoor and outdoor swimming pools ($r=0.989{\sim}0.999$, p<0.01). In the SBEG, the levels of BDCM and TTHMs showed a good correlation (r=0.913, p<0.01). In chlorine and ozone-chlorine disinfection systems at indoor swimming pools, pH, TOC and $KMnO_4$ consumption showed strong correlation with chloroform and TTHMs concentrations (p<0.01). In the SBEG, pH and TOC were also strongly correlated with chloroform (p<0.01). pH and TTHMs were correlated as well (p<0.05).

Keywords

References

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