Journal of Preventive Medicine and Public Health

The Korean Society for Preventive Medicine (대한예방의학회)
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Evaluation of Fourier Transform Near-infrared Spectrometer for Determination of Oxalate in Standard Urinary Solution

표준 요 시료 중 Oxalate의 측정을 위한 FT-NIR 분광기의 유용성 검정

  • Kim, Yeong-Eun (Department of Preventive Medicine, School of Medicine, Kyungpook National University) ;
  • Hong, Su-Hyung (Department of Dental Microbiology, School of Dentistry, Kyungpook National University) ;
  • Kim, Jung-Wan (Department of Dental Microbiology, School of Dentistry, Kyungpook National University) ;
  • Lee, Jong-Young (Department of Preventive Medicine, School of Medicine, Kyungpook National University)
  • 김영은 (경북대학교 의학전문대학원 예방의학교실) ;
  • 홍수형 (경북대학교 치의학전문대학원 구강미생물학교실) ;
  • 김정완 (경북대학교 치의학전문대학원 구강미생물학교실) ;
  • 이종영 (경북대학교 의학전문대학원 예방의학교실)
  • Published : 2006.03.01
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Abstract

Objectives : The determination of oxalate in urine is required for the diagnosis and treatment of primary hyperoxaluria, idiopathic stone disease and various intestinal diseases. We examined the possibility of using Fourier transform near-infrared (FT-NIR) spectroscopy analysis to quantitate urinary oxalate. The practical advantages of this method include ease of the sample preparation and operation technique, the absence of sample pre-treatments, rapid determination and noninvasiveness. Methods : The range of oxalate concentration in standard urine solutions was $0-221mg/{\ell}$. These 80 different samples were scanned in the region of 780-1,300 nm with a 0.5 nm data interval by a Spectrum One NTS FT-NIR spectrometer. PCR, PLSR and MLR regression models were used to calculate and evaluate the calibration equation. Results : The PCR and PLSR calibration models were obtained from the spectral data and they are exactly same. The standard error of estimation (SEE) and the % variance were $10.34mg/{\ell}$ and 97.86%, respectively. After full cross validation of this model, the standard error of estimation was $5,287mg/{\ell}$, which was much smaller than that of the pre-validation. Furthermore, the MCC (multiple correlation coefficient) was 0.998, which was compatible with the 0.923 or 0.999 obtained from the previous enzymatic methods. Conclusions : These results showed that FT-NIR spectroscopy can be used for rapid determination of the concentration of oxalate in human urine samples.

Keywords

References

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