Properties of Crease Resist Finishing for Cellulose Fabrics Treated with DMDHI and Waterborne Polyurethane by UV Irradiation

자외선 축합 가교반응에 의한 DMDHI/WPU 처리 면섬유의 방추가공 특성

  • Yang Yun-Kyu (School of Chemical Engineering, Chungnam National University) ;
  • Kang Suk-Hwan (School of Chemical Engineering, Chungnam National University) ;
  • Lee John-Tae (KT&G Central Research Institute) ;
  • Song Kyung-Heon (Department of Clothing and Textiles, Paichai University) ;
  • Hwang Taek-Seong (School of Chemical Engineering, Chungnam National University)
  • 양윤규 (충남대학교 바이오 응용화학부 화학공학과) ;
  • 강석환 (충남대학교 바이오 응용화학부 화학공학과) ;
  • 이존태 (KT&G 중앙연구원) ;
  • 송경헌 (배재대학교 의류패션학부) ;
  • 황택성 (충남대학교 바이오 응용화학부 화학공학과)
  • Published : 2006.02.01

Abstract

The waterborne polyurethane was synthesized by polytetramethylene glycol (PTMG) and isophorone diisocyanate (IPDI) with dimethylol propionic acid (DMPA). Physical properties of cellulose fabrics treated with 1,3-dimethyl-4,5-dihydoroxy-2-imidazolidone (DMDHI) containing waterborne polyurethane were investigated by UTM and FT-IR Spectrometer. It is known that optimized UV intensity and cure temperature are 450 Wand $170^{\circ}C$, respectively. Add-on(%) was increased with increasing concentration of resin and time. Therefore, the results showed that wrinkle recovery of the fabrics cured with UV were better than that of heat-cure. When PUD as an additive was treated together with DMDHI, tensile and bursting strength increased with increasing waterborne polyurethane concentration. Yellowness index(YI) values for UV-cured fabrics were lower than those of heat-cured ones.

Keywords

References

  1. S. M. Kim, T. S. Hwang, J. W. Park, Y. U. Kang, I. S. Jo, and S. G. Lee, 'Wrinkle Recovery Properties of Cellulose Fabrics Treated with DMDHI and Silicone-urethane Copolymer', J Korean Fiber Soc, 2004, 41, 100-105
  2. S. H. Cho, R. Kim, J. J. Park, and M. C. Lee, 'Durable Press Finishing of Silk/cotton Fabrics with BTCA(3) -The Study of Ester Crosslinkages of Silk/cotton Fabrics Treated with BTCA by FT-IR Spectroscopy', J Korean Soc Dyers Finishers, 2003, 15, 217-223
  3. Y. J. Choi and H. S. Ryu, 'A Study on the Sorption and Physical Properties of the BTCA Finished Cotton Fabrics', J Korean Soc Clothing Textiles, 1998, 22, 535-542
  4. N. R. Bertoniere and W. D. King, 'Pore Structure and Dyeability of Cotton Crosslinked with DMDHEU and with DMDHI', Text Res J, 1989, 59, 608-613 https://doi.org/10.1177/004051758905901009
  5. S. Shekarriz, P. Cohen, C. M. Carr, R. Mitchell, and C. Jones, 'Surface Chemical Analysis of 1,2,3,4-butanetetracarboxylic Acid Modified Cotton', J Mat Sci, 2003, 38, 2945-2957 https://doi.org/10.1023/A:1024469410216
  6. C. Schramm, W. H. Binder, and R. Tessadri, 'Durable Press Finishing of Silk/cotton Fabrics with 1,2,3,4-butanetetracarboxylic Acid and TEOS/GPTMS', J Sol Gel Sci Technol, 2004, 29, 155-165 https://doi.org/10.1023/B:JSST.0000023850.97771.7d
  7. Y. J. Choi and H. S. Ryu, 'Effect of the Changes in Micropore Structure on the Dyeability of BTCA Finished Cotton Fabrics', J Korean Soc Clothing & Textiles, 2003, 27, 1300-1306
  8. T. S. Hwang, 'Synthesis and Characterization of High-performance Fibrous Shape Memory Reagent Improved by UV Radiation', Korea Industrial Technology Foundation, 2004
  9. C. Hepburn, 'Polyurethane Elastomers', 2nd Ed., London, Elsevier, 1991
  10. J. H. Sanders and K. C. Frisch, 'Polyurethanes Chemistry and Technology', Interscience, NY, 1962
  11. D. W. Kang, Y. M. Kim, and D. K. Kweon, 'Synthesis and Characteristics of Rosinimides Modified with Polyarylsiloxane', Polymer(Korea), 1998, 22, 536-543
  12. S. K. Kim, K. S. Kim, T. K. Kim, and G. J. Oh, 'Synthesis and Physical Properties of Waterborne Polyurethane Microgels', Elastomer, 2000, 35, 281-287
  13. N. A. Ibrahim, H. M. Fahmy, T. M. Hassan, and Z. E. Mohamed, 'Effect of Cellulase Treatment on the Extent of Post-finishing and Dyeing of Cotton Fabrics', J Mat Proc Technol, 2005, 160, 99-106 https://doi.org/10.1016/j.jmatprotec.2004.04.370
  14. H. D. Kim and D. J. Lee, 'A Study on the Properties of UV - Cured Polyurethane Acrylates for Secondary Coating of Optical Fiber', J Korean Soc Clothing Text, 1998, 35, 739-745
  15. S. H. Cho and M. C. Lee, 'Durable Press Finishing of Silk/Cotton Fabrics with BTCA(1)', J Korean Soc Dyers Finishers, 2002, 14, 19-25
  16. S. I. Kang, B. G. Park, G. W. Lee, and Y. S. Jeong, 'Dyeing of BTCA Treated Cotton Fabrics with Phellodendron Amurense Rupr. Extract', J Korean Soc Clothing Text, 2003, 40, 458-462
  17. J. N. Im, E. S. Lee, and S. W. Ko, 'Durable Press Finish of Polyester/Cotton Fabrics with 1, 2, 3, 4-Butanetetracarboxylic acid', J Korean Soc Dyers Finishers, 1997, 34, 517-523