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LaNiO3 전극위에 (100)으로 배향된 (Na0.5Bi0.5)TiO3 박막의 성장

Growth of Highly (100) Oriented (Na0.5Bi0.5)TiO3 Thin Films on LaNiO3 Electrode

  • 발행 : 2006.02.01

초록

[ $(Na_{0.5}Bi_{0.5})TiO_3$ ][NBT] thin films were prepared on a highly (100) oriented $LaNiO_3[LNO]$ by sol-gel process. X-ray diffraction patterns of the NBT films annealed above $600^{\circ}C$ for 5 minutes have confirmed a highly (100) oriented growth and pseudocubic structure (a=3.884${\AA}$). The (l00) orientation factor increased from 90 to $99\%$ with increasing soaking time from 5 to 60 minutes at $600^{\circ}C$. The NBT films ($600^{\circ}C$/5 min,) have a flat and dense microstructure with large columnar grains, and their grain size are about 44 nm. The Au/NBT/LNO/Si hetero structure sample show a ferroelectric properties.

키워드

참고문헌

  1. 박민석, 서병준, 유영배, 문병기, 손세모, 정수태. ' $LaNiO_3$의 (100)배향성이 $Pb(Zr, Ti)O_3 $박막의 결정성장과 강유전성에 미치는 영향', 전기전자재료학회논문지, 18권, 4호, p. 338, 2005
  2. X. J. Meng, J. L. Sun, J. Yu, H. J. Ye, S. L.Gun, and J. H. Chu, 'Preparation of highly (100) oriented metallic $LaNiO_3$ films on Si substrates by a modified metalorganic decomposition technique', Applied Surface Science, Vol. 171, p. 68, 2001
  3. S. E. Park, S. J. Chung, I. T. Kim, and K. S. Hong, 'Nonstoichiornetry and the longrange cation ordering in crystals of $(Na_{1/2}Bi_{1/2})TiO_3'$', J. Am. Cer. Soc., Vol. 77, p. 2641, 1994
  4. 박민석, 김대영, 서병준, 김강언, 정수태, '열처리조건이 $LaNiO_3$의 졸-겔 박막의 배향성과 구조 및 저항성에 미치는 영향', 전기전자재료학회논문지, 17권, 8호, p. 859, 2004
  5. N. Ohashi, A. N. Soukhojak, G. W. Farrey, S. A. Sheets, and Y. M. Chiang, 'Liquid phase epitaxial growth of perovskite $(Bi,Na)TiO_3$ and solid solutions on $SrTiO_3$(001) substrates', IEEE CNF, Vol. 2, p. 553, 2001
  6. J . Suchanicz, ' The low-frequency dielectric relaxation $Na_{0.5}Bi_{0.5}TiO_3 $ceramics', Materials Science and Engineering B, Vol. 55, p. 114, 1998 https://doi.org/10.1016/S0921-5107(98)00188-3
  7. H. Nagata and T. Takenaka, 'Additive effects on electrical properties of $(Bi_{1/2}Na_{1/2}) TiO_3$ ferroelectric ceramics', Journal of the European Ceramic Society, Vol. 21, p. 1299, 2001 https://doi.org/10.1016/S0955-2219(01)00160-1
  8. X. Wang,' H. L. W. Chan, and C. I. Choy, 'Piezoelectric and dielectric properties of $CeO_2$ added $(Bi_{0.5}Na_{0.5})_{0.94}Ba_{0.06}TiO_3$lead free ceramics', Solid State Communication, Vol. 125, p. 395, 2003 https://doi.org/10.1016/S0038-1098(02)00816-5