DOI QR코드

DOI QR Code

Improvement of Permeation of Applied Multi-layer Encapsulation of Thin Films on Ethylene Terephthalate(PET)

고분자 기판위에 다층 구조의 박막형 보호층을 적용한 투습률 향상

  • Published : 2006.03.01

Abstract

In this paper, the inorganic-organic thin film encapsulation layer was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam, Sputter and Spin-Coater system, the various kinds of inorganic and organic thin-films were deposited onto the Ethylene Terephthalate(PET) and their interface properties between organic and inorganic layer were investigated. In this investigation, the SiON and Polyimide(PI) layer showed the most suitable properties. Under these conditions, the WVTR(water vapour transition rate) for PET can be reduced from level of $0.57\;g/m^2{\cdot}day$ (bare subtrate) to $1{\times}10^{-5}\;g/m^2{\cdot}day$ after application of a SiON and Polyimide layer. These results indicates that the SiON/PI/SiON/PI/PET barrier coatings have high potential for flexible organic light-emitting diode(OLED) applications.

Keywords

References

  1. A. B. Chang and M. A. Rothman, 'Thin film encapsulated flexible organic electro-luminescent displays', Appl, Phys. Lett., Vol. 83, No.3, p. 413, 2003 https://doi.org/10.1063/1.1594284
  2. C. W. Tang and S. A. VanSlyke, 'Organic electroluminescent diode', Appl. Phys, Lett., Vol. 51, No. 12, p. 913, 1987
  3. H. Lifka, H. A. van Esch, J. J., and W. M. Rosink, 'Thin film encapsulation of OLED displays with a NONON stack', Proceedings of the SID 2004, p. 1384, 2004
  4. D. J. Sekelik, E. V. Stepanov, S. Nazarenko, and A. Hiltner, 'Oxygen barrier properties of crystallized and talc-filled poly(ethylene terephthalater)', Journal of Polymer Science Vol. 37, p. 847, 1999 https://doi.org/10.1002/(SICI)1099-0488(19990415)37:8<847::AID-POLB10>3.0.CO;2-3
  5. D. S. Wuu, W. C. Lo, L. S. Chang, and R. H. Horng, 'Properties of $SiO_2$ -like barrier layers on polyethersulfone substrates by low-temperature plasma-enhanced chemical vapor deposition', Thin Solid Films 468 p. 105, 2004 https://doi.org/10.1016/j.tsf.2004.04.031
  6. A. Gruniger and Ph. Rudolf von Rohr, 'Influence of defects in $SiO_x$ thin films on their barrier properties', Thin Solid Films 459, p. 308, 2004 https://doi.org/10.1016/j.tsf.2003.12.146
  7. Z. Suo, E. Y. Ma, H. Gleskova, and S. Wagner, 'Mechanics of rollable and foldable film-on-foil electronics', Appl. Phys. Lett., Vol. 74, No.8, p. 1177, 1999 https://doi.org/10.1063/1.123478
  8. 김 훈, 김광호, 김재경, '무기 박막형 보호층을 이용한 고분자 유기 발광 다이오드의 특성평가', 한국전기전자재료학회 2003추계학술대회논문집, p. 60, 2003
  9. C. W. Tang and S. A. VanSlyke, 'Organic electroluminescent diode', Appl, Phys. Lett., Vol. 51, No. 22, p. 913, 1987
  10. C. J. Lee, R. B. Pode, D. G. Moon, and J. I. Han, 'Realization of an efficient top emitting organic light-emitting device with novel electrode', Thin Solid Film, Vol. 467, p. 201, 2004 https://doi.org/10.1016/j.tsf.2004.04.016
  11. S. H. Kwon, S. Y. Paik, O. J. Kwon, and J. S. Yoo 'Triple-layer passivation for longevity of polymer light-emitting diodes', Appl. Phy. Lett., Vol. 79, No: 26, p. 4450, 2001 https://doi.org/10.1063/1.1428770
  12. A. B. Chang, M. A. Rothman, S. Y. Mao, R. H. Hewitt, M. S. Weaver, J. A. Silvernail, M. Haek, J. J. Brown, X. Chu, L. Mora, T. Krajewski, and N. Rutherford, 'Thin film encapsulated flexible organic elecroluminescent displays', Appl. Phys. Lett., Vol. 83, No.3, p. 413, 2003 https://doi.org/10.1063/1.1594284