친수 및 소수화한 의류소재의 특성이 고형오구의 세척성에 미치는 영향 - 계면활성제의 흡착 및 섬유기질의 ${\zeta}Potential$ -

Influence of Characteristics of Textile Materials Finished with Hydrophilic and Hydrophobic Chemicals on Detergency of Particulate Soil - The Adsorption of Surfactant to Fabric and ${\zeta}Potential$ of Substrate -

  • Kang, In-Sook (Department of Clothing and Textiles, Changwon National University)
  • 발행 : 2006.12.31

초록

The steric stability by adsorption of surfactant to the labric and interfacial electrical condition such as the ${\zeta}-potential$ and the interaction energy between substrate and particle of fabric treated with hydrophilic and hydrophobic chemical was examined as a fundamental environment of detergency of particulate soil. The hydrophilic and hydro-phobic finish for PET fabric were treated with polyester, silicone and fluorine organic compound of resin respectively. The adsorption of anionic and nonionic surfactant to fabric were measured by abbott method and HPLC analysis. And the ${\zeta}-potential$ of particles and fabric were measured by microelectrophoresis and streaming potential method, respectively. The potential energy of interaction between u·Fe201 particle and fiber were calculated by using the heteroco-agulation theory for a sphere-plate model. The adsorption of anionic and nonionic surfactant to polyester fabric was largely influenced by concentration of surfactant and ionic strength as compared to concentration of finishing agent and adsorption time of surfactant regardless of chemicals. And the adsorption of surfactant to fabric treated with hydrophobic chemicals was higher than fabric treated with hydrophilic chemicals. With the increase of concentration of finishing agent, the ${\zeta}-potential$ of fiber treated with hydrophilic and hydrophobic chemical were converted from negative to positive regardless of chemicals. And the potential energy of interaction between ${\alpha}-Fe_2O_3$ particle and fiber were adhesion force in fabric treated with hydrophobic chemical and repulsion force in fabric treated with hydrophilic chemical.

키워드

참고문헌

  1. S. Rema, M. Anuradha, and V. G. Kumar, 'Effect of Charge and Hydrophobicity on Adsorption of Modified Starches on Polyester', J Colloid and Interface Sci, 1999, 220, 260-268 https://doi.org/10.1006/jcis.1999.6506
  2. J. Zimoch, W. Hreczuch, and Kedzierzyn-Kozle, 'Detergency and Dynamic Surface Tension Reduction qf Oxyethylated Fatty Acid Methyl Esters', Tenside Surf Det, 2002, 39, 8-16
  3. D. J. Shaw, 'Introduction to Colloid and Surface Chemistry', Butter-Worths, London, 1970, pp. 161-183
  4. I. Krznaric and N. Kally, 'Stability of Ag/I Colloid in the Presence of Ionic Surface Active Agents and Electrolytes in Aqueous Medium', Tenside Surf Det, 1979, 16(5), 252-261
  5. N. Kallay, I. Krznaric, and Z. Cegelj, 'The Mechanism of Interactions between Nonionic Surface Active Agents and Lyophobic Colloids', Colloid & Polymer Sci, 1979, 257, 75-86 https://doi.org/10.1007/BF01539020
  6. D. V. Robert and J. V. Marjorie, 'Collid and Interface Chemistry', Addison- Wesley, London, 1983, pp. 164-167
  7. I. S. Kang, 'Effect of Stability by Adsorption of Surfactant on. the .Detergency of Particulate Soil Anionic/nortionic Surfactant Mixed Solution(II)', J Korean Fiber Soc, 2002, 39(4), 485-492
  8. I. S. Kang and S. R. Kim, 'Interfacial Electrical Studies on Adhesion of Hematite Particle to Polyester Fabric and Its Removal from the Fabric(part 1)', J Korean Soc Clothing and Text, 1993, 17(3), 380-390
  9. E. Matijevic and P. Scheiner, 'Ferric Hydrous Oxide Sols', J Colloid Interface Sci, 1978, 63(3), 509-524 https://doi.org/10.1016/S0021-9797(78)80011-3
  10. D. C. Abbott, 'The Colorimetric Determination of Anionic Surface-active Materials in Water', Analyst, 1962, 87, 286-293 https://doi.org/10.1039/an9628700286
  11. B. B. Sithole, B. Zvilichovsky, C. LaPointe, and L. H. Allen, 'Adsorption of Aqueous Nonylphenol Ethoxylate Surfactants on Metal Sample Loops : Effect on Qunantitation by Lipuid Chromatography', J Assoc Off Anal Chem, 1990, 73, 322-324
  12. B. B. Sithole and L. H. Allen, 'Determination of Nonionic Nonylphenol Ethoxylate Surfactants in 'Pulp and Paper Mill Process Samples by Spectrophotometry and Liquid Chromatography', J Assoc Off Anal Chem, 1989, 72, 273-276
  13. W. G. Cuter and R. C. Davis, 'Detergency; Theory and Test Methods, Surfactant Science Series', Vol. 5, Marcel Dekker, New York, 1972, pp.95-96
  14. I. S. Kang and B. J. Kim, 'Effect of Electrolyte on Adhesion of Particulate Soil to Fabric in the Surfactant Solution', J Korean Soc Clothing and Text, 2002, 25(8), 1465-1474
  15. T. Imamura and E, Tokiwa, 'The Effect on the Deposition of Ferric Oxide Particles onto Various Fabrics', Nippon Kagaku Kaishi, 1973, 4, 648-660