Resources Recycling (자원리싸이클링)

The Korean Institute of Resources Recycling (한국자원리싸이클링학회)
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Catalytic decomposition of HDPE over Al-MCM-48 using TGA and Py-GC/FID

TGA와 Py-GC/FID를 이용한 Al-MCM-48상에서 HDPE의 촉매(觸媒) 열분해(熱分解)

  • Kim, Young-Min (Dept. of Environmental System Engineering, Hallym Univ.) ;
  • Kim, Seung-Do (Dept. of Environmental System Engineering, Hallym Univ.) ;
  • Park, Young-Kwon (Faculty of Environmental Engineering, University of Seoul) ;
  • Kim, Ji-Man (Dept. of Chemistry, Sungkyunkwan University) ;
  • Jeon, Jong-Ki (Dept. of Chemical Engineering, Kongju University)
  • 김영민 (한림대학교 환경시스템공학과) ;
  • 김승도 (한림대학교 환경시스템공학과) ;
  • 박영권 (서울시립대학교 환경공학부) ;
  • 김지만 (성균관대학교 화학과) ;
  • 전종기 (공주대학교 화학공학부)
  • Published : 2006.10.27
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Abstract

Al-MCM-48 was used as a catalyst to decompose high density polyethylene(HDPE). Catalytic activity of Al-MCM-48 was compared with those of Al-MCM-41, Beta, and ZSM-5. Catalytic decomposition rate over Al-MCM-48 was much higher than at of non-catalytic pyrolysis only. Compared to other catalysts, Al-MCM-48 revealed the little higher activation energy value. The progressive deactivation behavior of the catalysts has also studied. ZSM-5 and Al-MCM-48 showed slower deactivation rates than Al-MCM-41 and Beta. Pyrolysis coupled with gas chromatographic separation and flame ionization detection (Py-GC/ FID) was also performed to assess the characteristics of pyrolysis products. ZSM-5 gave a higher fraction of gaseous products ($C_1-C_4$). Al-MCM-41 and Beta produced mainly $C_5-C_{12}$ products. The selectivity to oil product ($C_5-C_{22}$) obtained with Al- MCM-48 is higher an that with the other catalysts employed in this study.

본 연구는 Al-MCM-48을 이용하여 HDPE를 촉매 분해하는 것으로, Al-MCM-48의 촉매 활성을 Al-MCM-41, Beta, ZSM-5와 비교하였다. Al-MCM-48를 사용한 열분해 활성은 무촉매 열분해의 활성보다 매우 높았다. 다른 촉매와 비교했을 때 Al-MCM-48의 활성화 에너지는 거의 차이가 없었다. 촉매의 점진적인 비활성화 경향도 조사하였다. ZSM-5와 Al-MCM-48은 Al-MCM-41과 Beta보다 비활성화 경향이 낮았다. Py-GC/FID(pyrolyzer)를 이용하여 열분해 생성물의 특성에 대하여 분석하였다. 그 결과 ZSM-5 촉매를 사용한 경우에는 $C_1-C_4$ 범위의 기상 생성물이 많이 생성되었다. Al-MCM-41과 Beta를 사용한 경우에는 주로 $C_5-C_{12}$ 범위의 화합물이 생성되었다. Al-MCM-48은 다른 촉매들에 비해 $C_5-C_{22}$ 범위의 오일 생성물에 대해서 높은 선택도를 나타내었다.

Keywords

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