Comparison of Venting Modes for Bench Scale Treatment of Diesel Contaminated Soil

디젤오염토양의 Bench Scale 처리에 있어서 벤팅모드 비교

  • Kim, Young-Am (Han-Sin Environment Co. Ltd.) ;
  • Lee, Yong-Hee (Research Institute for Basic Science, Dongeui University) ;
  • Lee, Dong-Sun (Division of Materials & Fine Chemistry and Department of Medical Administration, Dongeui Institute & Technology) ;
  • Suh, Myung-Gyo (Division of Materials & Fine Chemistry and Department of Medical Administration, Dongeui Institute & Technology)
  • 김영암 ((주)한신환경) ;
  • 이용희 (동의대학교 기초과학연구소) ;
  • 이동선 (동의과학대학 신소재생활과학계열 및 의무행정과) ;
  • 서명교 (동의과학대학 신소재생활과학계열 및 의무행정과)
  • Published : 2006.10.31

Abstract

Bioventing efficiency was compared in a continuous and an intermittent(6hr injection and 6hr rest) air injection mode. Two lab-scale columns which packed with 5 kg of soil artificially contaminated by diesel oil were operated. The columns were maintained at the $25^{\circ}C{\pm}2.5$ in order to minimize the effect of exterior temperature variation. The flow rate of air injection mode were maintained constantly at the flow rate of 10 ml/min. The moisture of the columns was stably maintained at $60{\sim}80%$ of field capacity. The nutrient compounds were added to make C:N:P ratio as 100:10:l. The continuous and intermittent injection modes showed 67.56% and 69.63% reduction of initial TPH concentration during 90 days, respectively. Two venting modes showed similar results in the analysis of the trends of the hydrocarbon utilizing bacterial counts for operating periods. The carbon dioxide production rate of the continuous injection mode was higher than that of intermittent injection mode. The loss of diesel oil by volatilization in the continuous and intermittent injection modes were about 5% and 1%, respectively. The lower volatilization loss in the intermittent injection mode suggested that the biodegradation of TPH in the intermittent injection mode was greater than that of the continuous mode. These results suggested that the intermittent injection mode is more efficient than the continuous venting mode.

Keywords

References

  1. 문경환, 김우현, 이병철, 김덕환 : 마이크로파에 의한 휘발성 유기토양오염물질제거에 대한 연구. 한국환경보건학회지, 22(3), 116-122, 1996
  2. 이혜령, 고경숙, 임경택 : 토양상에 의한 Trichloroethylene 처리에 관한 연구. 한국환경보건학회지, 24(3), 41-47, 1998
  3. Sims, R. C. : Soil remediation techniques at uncontrolled hazardous waste sites; a critical review. Journal of the Air & Waste Management Association, 40(5), 704-732, 1990 https://doi.org/10.1080/10473289.1990.10466716
  4. 박천보, 허병기, 윤현식 : 유류 오염지역으로부터 분리된 균주를 이용한 디젤류의 분해. 한국생물공학회지, 16(6), 632-637, 2001
  5. 김일배, 홍원학, 이학성, 서명교, 서정호 : 비젼시스템을 이용한 토양미생물 관측장비 개발. 한국환경보건학회지, 30(2), 108-114, 2004
  6. 최정영, 남궁완, 박준석, 황의영 : 디젤초기농도가 오염토양의 콤포스팅 처리에 미치는 영향. 한국 유기성자원학회지, 10(1), 120-127, 2002
  7. 임계량, 박준석, 황의영, 남궁완 : 초기농도가 파일럿 규모의 디젤오염토양콤포스팅처리에 미치는 영향. 한국환경보건학회지, 28(5), 35-41, 2002
  8. Jorgensen, K. S., Puustinen, J. and Suoritti, A. M. : Bioremediation of pertrolelum hydrocarbon contaminated soil by composting in biopiles. Environmental Pollution, 107, 245-254, 2000 https://doi.org/10.1016/S0269-7491(99)00144-X
  9. Laine, M. M., Haario, J. and Jorgensen, K. S. : Microbial functional activity during composting of chlorophenol contaminated sawmill soil. Journal of Microbiological Methods, 30, 21-32, 1997 https://doi.org/10.1016/S0167-7012(97)00040-7
  10. 이종열, SBC system(Mobile SVE & Bioventing coexisiting system). News & Information for Chemical Engineers, 21(4), 491-494, 2003
  11. 윤석표, 차명철, 류범수, 윤범한 : Soil vapor extraction과 Biobenting 기술의 원리와 적용에 대한 고찰. 한국폐기물학회지, 13(1), 161-171, 1996
  12. 박준석, 김승호, 박연구 : 온라인 모니터링에 의한 디젤오염토양의 토양증기추출 공정시 추출모드 평가. 한국유기성자원학회지, 11(4), 90-96, 2003
  13. Atlas, R. M. and Bartha, R. : Hydrocarbon biodegraddition and oil spill bioremediation, In Marshall KC(ed) Advances in microbial ecology 12 Plenum, New York, 287-338, 1992
  14. Moller, J. and Winther, P. : Bioventing of diesel oilcontaminated soil. Journal of Industrial Microbiology, 16, 110-116, 1996 https://doi.org/10.1007/BF01570070
  15. Margesin, R. and Schinner F. : Monitoring of bioremediation by soil biological activities. Chemosphere, 40, 339-346, 2000 https://doi.org/10.1016/S0045-6535(99)00218-0