Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
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Emission Characteristics of Carbonyl Compounds from Major Industrial Sectors in the Ban-Wall Industrial Complex, Korea

카보닐 계열의 배출 특성과 그에 따른 악취 발생 기여도 비교 연구: 반월공단내 주요 산업시설물들을 중심으로

  • Hong, Y.J. (Department of Earth & Environmental Sciences, Sejong University) ;
  • Jeon, E.C. (Department of Earth & Environmental Sciences, Sejong University) ;
  • Kim, K.H. (Department of Earth & Environmental Sciences, Sejong University)
  • 홍윤정 (세종대학교 지구환경과학과) ;
  • 전의찬 (세종대학교 지구환경과학과) ;
  • 김기현 (세종대학교 지구환경과학과)
  • Published : 2006.10.31
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Abstract

The carbonyl compounds in the atmosphere belong to one of the regulatory pollutants for the malodor control designated by the Korean Ministry of Environment(KMOE). In the present study, the emission concentration levels of carbonyl compounds were measured along with a number of criteria odor pollutants from a total of 47 individual companies(June 2004 to January 2005). The results of our study showed that a number of carbonyl compounds(such as formaldehyde, acetaldehyde, acetone, and butyraldehyde) maintained significantly high mean concentrations of 298 to 372 ppb. In contrast, other carbonyl compounds were low enough with the mean valves of 0.54 to 19.1 ppb. It was found that except for such industries as metal production or leather processing, their emissions were generally quite significant. If the measured values were evaluated in terms of malodor intensity, butyraldehyde appeared to be the most significant contributor to the malodor release. According to the measurements made in strong source areas, it can be concluded that several carbonyl compounds(acetaldehyde, propionaldehyde, butyraldehyde, isovaleraldehyde, and valeraldehyde) are useful enough to diagnose malodor release from those source areas. It should also be addressed that a number of carbonyl compounds added newly as the result of malodor control legislation were not sensitive enough to diagnose malodor release from such sources.

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References

  1. 김기현, 최여진, 홍윤정, 사재환, 박종호, 전의찬, 최청렬, 구윤서(2005a) 반월공단내 주요 산업시설물들의 대기 배출시설을 중심으로 한 주요 악취성분의 배출특성 및 배출원별 악취인자 선별 방식에 대한 예비연구, 한국대기환경학회지, 21(2), 215-226
  2. 김기현, 주도원, 최여진, 홍윤정, 사재환, 박종호, 전의찬, 최청렬, 구윤서 (2005b) 안산시 주거지역을 중심으로한 환경대기 중 휘발성 유기 화합물과 황계열 성분의 온라인 연속 측정 연구, 한국대기환경학회지, 21(2), 215-226
  3. 양성봉, 박상진, 김만구, 김덕현(2003) 안산 반월시역 악취배출원 조사 및 저감 방안 연구 (보고서). 국립환경연구원
  4. 조양희, 박선오, 우수민, 함태식 (2003) 식품의 종이 포장재 및 보장재로부터 이행되는 잔류 포름 알데하이드의 분석. 한국환경분석학회지, 6(3), 213-217
  5. 조석연, 황용우, 황상순 (2003) 인천 서구지역 악취배출원조사 및 저감방안 연구(보고서). 인천지역 환경기술개발 센터
  6. 홍윤정, 김기현 (2005) 대기 중 카보닐 계열 성분의 분석기법의 연구: 포름알데하이드와 DNPH의 반응 특성을 중심으로. 한국분석과학학회지, 18(1), 42-49
  7. 황윤정, 박상곤, 백성옥(1998) 공기 중 포름알데하이드 측정을 위한 크로모트로핀산법과 DNPH/HPLC방법의 비교 평가, 한국대기보전학회지, 14(5), 519-524
  8. Feng, Y., S. Wen, Y. Chen, X. Eang, H. Lu, X. Bi, G. Sheng, and J. Fu (2004) Ambient levels of carbonyl compounds and their sources in Guangzhou, China, Atmospheric Environment, 39, 1789-1800 https://doi.org/10.1016/j.atmosenv.2004.10.009
  9. Grosjean, D., E. Grosjean, and L.F.R. Moreira (2002) Speciated ambient carbonyls in Rio de Janeiro, Brazil., Environmental Science and Technology, 36, 1389-1395 https://doi.org/10.1021/es0111232
  10. Grosjean, E., E.L. Williams II, and D. Grosjean (1993) Ambient levels of formaldehyde and acetaldehyde in Atlanta, Georgia, J. Air Waste Manage. Assoc, 43, 469-474
  11. Grosjean, E., D. Grosjean, M.P. Fraser, and G.R. Cass (1996) Air quality model evaluation data for organics. 2. C1-C14 carbonyls in Los Angeles air, Environmental Science and Technology, 30, 2687-2703 https://doi.org/10.1021/es950758w
  12. Nagata, Y. (2003) Odor intensity and odor threshold value. Journal of Japan Air Cleaning Association, 41(2), 17-25
  13. Nagata, Y. and N. Takeuchi (1980) Relationship between concentration of odorants and odor intensity, Bulletin of Japan Environmental Sanitation Center, 7, 75-86
  14. Viskari, E.L., M. Vartiainen, and P. Pasanen (2000) Seasonal and diurnal variation in formaldehyde and acetaldehyde concentrations along a highway in Eastern Finland, Atmospheric Environment, 34, 917-923 https://doi.org/10.1016/S1352-2310(99)00307-6