Bulletin of the Korean Chemical Society

  • 제27권4호
  • /
  • Pages.463-472
  • /
  • 2006
  • /
  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Regulation of Stereoselectivity and Reactivity in the Inter- and Intramolecular Allylic Transfer Reactions

  • Yu, Chan-Mo (Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University) ;
  • Youn, Jin-soup (Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University) ;
  • Jung, Hee-Keum (Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University)
  • 발행 : 2006.04.20
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⟨ 이전 논문 다음 논문 ⟩

초록

The preparation of enatiomerically enriched homoallylic alcohols through asymmetric addition of chiral allylic transfer reagents and allylating reagents with chiral catalysts to the carbonyl functionalities represents an important chemical transformation. Excellent progress has been made over past decade in the development and application of catalytic asymmetric allylic transfer reactions. In this account, our efforts for the various intermolecular allylic transfer reactions such as allylation, propargylation, allenylation, and dienylation utilizing accelerating strategy and sequential allylic transfer reactions to achieve multiple stereoselection mainly using transition metal catalysts are described.

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