Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Syntheses and Crystal Structures of Xylyl-Bridged NO2S2-Donor Macrocycles and Binuclear Mercury(II) Complex

  • Lee, Ji-Eun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Jin, Yong-ri (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Seo, Joo-beom (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Yoon, Il (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Song, Mi-Ryoung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, So-Young (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Park, Ki-Min (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
  • Published : 2006.02.20
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Abstract

Isomeric series of dilinked $NO_2S_2$ macrocycles ($L^2$: para-, $L^3$: meta- and $L^4$: ortho-linked) capable of binuclear complexing ability were prepared from its monomeric analog $L^1$ in reasonable yields except ortho-type reaction, which led to mixture due to the formation of monomer-type macrocyclic quaternary ammonium bromide $L^5$. Moreover, L2 (as $2HNO_3$ form) and $L^5$ were confirmed by an X-ray crystallography. Reaction of $HgCl_2$ with $L^2$ yielded a binuclear complex $[Hg_2(L^2)Cl_4]$. In the complex, each mercury(II) has a distorted tetrahedral environment made up of S and N donors from an exodentate $L^2$ and two coordinated Cl atoms.

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