Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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New Stigmastane Steroids Constituents from Rice Hulls of Oryza sativa and Inhibitory Activity on Radish seed

  • Jeong, Il-Min (Department of Applied Life Sciences, Konkuk University) ;
  • Ali, Mohd (Faculty of Pharmacy, Hamdard University) ;
  • Khanh, Tran Dang (Department of Applied Life Sciences, Konkuk University) ;
  • Choung, Myoung-Gun (Department of Pharmacognosy Material Development, Samcheok National University) ;
  • Park, Hong-Jae (National Institute of Agricultural Biotechnology, RDA) ;
  • Ahmad, Ateeque (Department of Applied Life Sciences, Konkuk University)
  • Published : 2006.01.20
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Abstract

Two new compounds 1'-(stigmast-11,20(21),25-trien 3$\alpha$,9$\alpha$-diolyl)-3'-(pimara-11,15-dien-3$\alpha$-olyl) glycerol (1) and stigmast-5-en-3$\alpha$,26-diol (2) along with known fatty acids n-hexacosanoic acid (3) and hexadecanoic acid (4), have been isolated from the methanol extract of rice hulls of Oryza sativa. The structures of the compounds were elucidated using 1D and 2D NMR spectral methods, viz; $^1H, ^{13}C, ^{13}C$-DEPT, $^1H-^1H$ COSY, $^1H-^{13}C$ HETCOR, HSQC and HMBC aided by IR, EIMS, FABMS and HRFABMS. Compound (1) showed inhibition to radish germination, growth of shoot and root length.

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