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Photoreactions of (2-Alkoxymethylphenyl)pentamethyldisilanes

  • Park, Seung-Ki (Department of Chemistry, College of Natural Sciences, The University of Suwon)
  • Published : 2006.09.20
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초록

Photolysis of (2-hydroxymethylphenyl)pentamethyldisilane 1 in methanol provides a novel intramolecular photoproduct 4 via silene intermediate 2 but the photoreaction of (2-acetoxymethyl- or allyloxymethylphenyl) pentamethyldisilanes 5 or 10 in methanol affords unexpected photoproducts 8 or 13, respectively, instead of expected intramolecular photoproducts.

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참고문헌

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  6. Photoreactions of (2-Acetoxyphenyl)pentamethyldisilane vol.32, pp.8, 2011, https://doi.org/10.5012/bkcs.2011.32.8.3155
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