Bulletin of the Korean Chemical Society

  • 제27권8호
  • /
  • Pages.1171-1174
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Coupling Reaction of CO2 with Epoxides by Binary Catalytic System of Lewis Acids and Onium Salts

  • Bok, Taekki (Department of Molecular Science and Technology, Ajou University) ;
  • Noh, Eun Kyung (Department of Molecular Science and Technology, Ajou University) ;
  • Lee, Bun Yeoul (Department of Molecular Science and Technology, Ajou University)
  • 발행 : 2006.08.20
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⟨ 이전 논문 다음 논문 ⟩

초록

Various off-the-shelf Lewis acids in conjunction with various onium salts are screened for coupling reaction of $CO_2$ with epoxides. Among the tested ones, $VCl_3/n-Bu_4NOAc$, $VCl_3/(n-Bu_4NCl$ or PPNCl), $FeCl_3/ n-Bu_4NOAc$, and $FeCl_3/ n-Bu_4NOAc$are proved to be highly active. Propylene oxide, epichlorohydrin, styrene oxide, and cyclohexene oxide can be converted over 90% yields to the corresponding cyclic carbonates without the use of organic solvents under mild conditions by 0.1-1.0 mol% catalyst charge.

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