Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Methanol Oxidation Effect on Carbon Supported Pt Particles Studied by 13C NMR, XRD, and TEM

  • Han, Kee Sung (Analytical Research Division, Daegu Center, Korea Basic Science Institute) ;
  • Han, Oc Hee (Analytical Research Division, Daegu Center, Korea Basic Science Institute)
  • Published : 2006.08.20
Download PDF
⟨ Previous Next ⟩

Abstract

Methanol oxidation effect on carbon supported Pt was investigated as a function of Pt content in a sample which is closely correlated with Pt particle sizes. After prolonged methanol oxidation the Pt particle size did not change within the experimental error ranges. The $^{13}C$ chemical shift and linewidth of CO adsorbed on Pt show non-linear behavior simply due to the Pt particle size difference. The Pt size variation difference between this work and the previous reports of the particle growths is explained by the experimental temperature difference.

Keywords

References

  1. Antolini, E. Mater. Chem. & Phys. 2003, 78, 563 https://doi.org/10.1016/S0254-0584(02)00389-9
  2. Acres, G. J. K.; Hards, G. A. Phil. Trans. R. Soc. Lond. A 1996, 354, 1671 https://doi.org/10.1098/rsta.1996.0072
  3. Arico, A. S.; Srinivasan, S.; Antonucci, V. Fuel Cells 2001, 1, 133 https://doi.org/10.1002/1615-6854(200107)1:2<133::AID-FUCE133>3.0.CO;2-5
  4. Prabhuram, J.; Wang, X.; Hui, C. L.; Hsing, I.-M. J. Phys. Chem. B 2003, 107, 11057 https://doi.org/10.1021/jp0357929
  5. Teranishi, T.; Hosoe, M.; Tanaka, T.; Miyake, M. J. Phys. Chem. B 1999, 103, 3818 https://doi.org/10.1021/jp983478m
  6. Frelink, T.; Visscher, W.; van Veen, J. A. R. J. Electroanal. Chem. 1995, 382, 65 https://doi.org/10.1016/0022-0728(94)03648-M
  7. Han, K. S.; Han, O. H. Electrochim. Acta 2001, 47, 519 https://doi.org/10.1016/S0013-4686(01)00773-3
  8. Han, K. S.; Han, O. H.; Babu, P. K. J. Electrochem. Soc. 2005, 152, J131 https://doi.org/10.1149/1.2077327
  9. Stakheev, A. Yu.; Kustov, L. M. Appl. Catal. A: General 1999, 188, 3 https://doi.org/10.1016/S0926-860X(99)00232-X
  10. Rodriguez-Reinoso, F. Carbon 1998, 36, 159 https://doi.org/10.1016/S0008-6223(97)00173-5
  11. Antolini, E. J. Mater. Sci. 2003, 38, 2995 https://doi.org/10.1023/A:1024771618027
  12. Kinoshita, K.; Routsis, K.; Bett, J. A. S. Electrchim. Acta 1973, 18, 953 https://doi.org/10.1016/0013-4686(73)87027-6
  13. Triaca, W. E.; Arvia, A. J. J. Appl. Electrochem. 1990, 20, 347
  14. Hu, C.-C.; Liu, K.-Y. Electrochim. Acta 1999, 44, 2727 https://doi.org/10.1016/S0013-4686(98)00400-9
  15. Surnev, S.; Schoiswohl, J.; Kresse, G.; Ramsey, M. G.; Netzer, F. P. Phys. Rev. Lett. 2002, 89, 246101
  16. Thostrup, P.; Kruse Vestrgaard, E.; An, T.; Laegsgaard, E.; Besenbacher, F. J. Chem. Phys. 2003, 118, 3724 https://doi.org/10.1063/1.1540611
  17. Rasko, J. J. Catal. 2003, 217, 478 https://doi.org/10.1016/S0021-9517(03)00147-7
  18. van Beurden, P.; Bunnik, B. S.; Kramer, G. J. Phys. Rev. Lett. 2003, 14, 066106
  19. Baily, C. J.; Surman, M.; Russell, A. E. Surf. Sci. 2003, 523, 111 https://doi.org/10.1016/S0039-6028(02)02346-4
  20. Moula, Md. G.; Mishra, A. B. P.; Rzeznicka, I.; Kislyuk, M. U.; Liu, S.; Ohno, Y.; Matsushima, T. Chem. Phys. Lett. 2001, 341, 225 https://doi.org/10.1016/S0009-2614(01)00495-X
  21. van Beurden, P.; Kramer, G. J. J. Chem. Phys. 2004, 121, 2317 https://doi.org/10.1063/1.1763834
  22. Rzeznicka, I.; Moula, Md. G.; de la Garza, L. M.; Ohno, Y.; Matsushima, T. J. Chem. Phys. 2003, 119, 9829 https://doi.org/10.1063/1.1615473
  23. Cheng, X.; Chen, L.; Peng, C.; Chen, Z.; Zhang, Y.; Fan, Q. J. Electrochem. Soc. 2004, 151, A48 https://doi.org/10.1149/1.1625944
  24. Wilson, M. S.; Garzon, F. H.; Sickafus, K. E.; Gottesfeld, S. J. Electrochem. Soc. 1993, 140, 2872 https://doi.org/10.1149/1.2220925
  25. Alderucci, V.; Passalacqua, E.; Giordano, N.; Antonucci, P. L.; Parmigiani, F.; Ricci, N. J. Appl. Electrochem. 1990, 20, 235 https://doi.org/10.1007/BF01033600
  26. Jenkins, R.; Snyder, R. L. Introduction to X-ray Powder Diffractometry; Wiley Interscience: New York, 1996; p 89
  27. Adams, C. R.; Benesi, H. A.; Curtis, R. M.; Meisenheimer, R. G. J. Catal. 1962, 1, 336 https://doi.org/10.1016/0021-9517(62)90061-1
  28. van der Klink, J. J.; Brom, H. B. Prog. NMR Spectrosc. 2000, 36, 89 https://doi.org/10.1016/S0079-6565(99)00020-5
  29. van der Klink, J. J. Adv. Catal. 2000, 44, 1
  30. Fraissard, J. Catalysis Today 1999, 51, 481 https://doi.org/10.1016/S0920-5861(99)00035-8
  31. Wu, J.; Day, J. B.; Franaszczuk, K.; Montez, B.; Oldfield, E.; Wieckowski, A.; Vuissoz, P. A.; Ansermet, J. P. J. Chem. Soc., Faraday Trans. 1997, 93(6), 1017 https://doi.org/10.1039/a603611b
  32. Babu, P. K.; Tong, Y. Y.; Kim, H. S.; Wieckowski, A. J. Electroanal. Chem. 2002, 524-525, 157 https://doi.org/10.1016/S0022-0728(02)00674-5
  33. Babu, P. K.; Oldfield, E.; Wieckowski, A. In Modern Aspects of Electrochemistry; Vayenas, C. G.; Conway, B. E.; White, R. E., Eds.; Kluwer Academic/Plenum Publishers: New York, 2003; Vol. 36, Ch. 1
  34. Rice, C.; Tong, Y.; Oldfield, E.; Wieckowski, A. Elecrochim. Acta 1998, 43, 2825 https://doi.org/10.1016/S0013-4686(98)00023-1
  35. Ross, Jr., P. N. In Electrocatalysis; Lipkowski, J.; Ross, P. N., Eds.; Wiley-VCH: New York, 1988; Ch. 2
  36. Tong, Y.; Rice, C.; Wieckowski, A.; Oldfield, E. J. Am. Chem. Soc. 2000, 122, 1123 https://doi.org/10.1021/ja9922274
  37. Tong, Y. Y. J. Magn. Reson. A 1996, 119, 22 https://doi.org/10.1006/jmra.1996.0047
  38. Min, M. K.; Cho, J.; Cho, K.; Kim, H. Electrochim. Acta 2000, 45, 4211 https://doi.org/10.1016/S0013-4686(00)00553-3
  39. Tong, Y.; Rice, C.; Godbout, N.; Wieckowski, A.; Oldfield, E. J. Am. Chem. Soc. 1999, 121, 2996 https://doi.org/10.1021/ja9830492
  40. Park, S.; Xie, Y.; Weaver, M. J. Langmuir 2002, 18, 5792 https://doi.org/10.1021/la0200459
  41. Park, S.; Tong, Y. Y.; Wieckowski, A.; Weaver, M. J. Langmuir 2002, 18, 3233 https://doi.org/10.1021/la0113825
  42. Lu, C.; Rice, C.; Masel, R. I.; Babu, P. K.; Waszczuk, P.; Kim, H. S.; Oldfield, E.; Wieckowski, A. J. Phys. Chem. B 2002, 106, 9581 https://doi.org/10.1021/jp020169u
  43. Rudaz, S. L. Ph.D. Thesis, University of Illinois at Urbana-Champaign: 1984

Cited by

  1. Comparison of CO on Carbon-supported Pt Catalysts Prepared by CO Gas Bubbling and Methanol Dehydrogenation vol.28, pp.12, 2006, https://doi.org/10.5012/bkcs.2007.28.12.2442