Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Macrocyclic Isomers with S2O-Donor Set as Silver(I) Ionophores

  • Park, Sung-Bae (Department of Chemistry, Inje University) ;
  • Yoon, Il (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Seo, Joo-beom (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Kim, Hyun-Jee (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Kim, Jae-Sang (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
  • Published : 2006.05.20
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Abstract

$S_2O$-donor macrocyclic isomers incorporating a xylyl group in o- ($L^1$), m- ($L^2$) and p-positions ($L^3$) extract no metal ions except silver(I) from aqueous to chloroform phase. And the magnitudes of %Ex for silver(I) are in the order of $L^1$ > $L^2$ > $L^3$. Taking this result into account, $L^1$-$L^3$ were utilized as membrane active components to prepare potentiometric silver(I)-selective electrodes. The proposed macrocycles-based electrodes E1 ($L^1$), E2 ($L^2$) and E3 ($L^3$) exhibited comparable results which show considerable selectivity toward silver(I) over alkali, alkali earth and other transition metal ions. Comparative NMR study on $L^1$-$L^3$ and their complexes with silver(I) in solution was also accomplished. In addition, a unique sandwich-type complex $[Ag(L^1)_2]CIO_4$ was prepared from the assembly reaction of $L^1$ with $AgClO_4$ and structurally characterized by an X-ray diffraction analysis.

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References

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