Bulletin of the Korean Chemical Society

  • 제27권10호
  • /
  • Pages.1633-1637
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Selective Vapor-Phase Deposition of Conductive Poly(3,4-ethylenedioxythiophene) Thin Films on Patterned FeCl3 Formed by Microcontact Printing

  • Lee, Bo H. (Department of Chemistry, Hanyang University) ;
  • Cho, Yeon H. (Department of Chemistry, Hanyang University) ;
  • Shin, Hyun-Jung (School of Advanced Materials Engineering, Kookmin University) ;
  • Kim, Jin-Yeol (School of Advanced Materials Engineering, Kookmin University) ;
  • Lee, Jae-gab (School of Advanced Materials Engineering, Kookmin University) ;
  • Lee, Hai-won (Department of Chemistry, Hanyang University) ;
  • Sung, Myung M. (Department of Chemistry, Hanyang University)
  • 발행 : 2006.10.20
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초록

We demonstrate a selective vapor-phase deposition of conductive poly(3,4-ethylenedioxythiophene) (PEDOT) thin films on patterned $FeCl_3$. The PEDOT thin films were grown on various substrates by using the vapor-phase polymerization of ethylenedioxythiophene (EDOT) with $FeCl_3$ catalytic layers at 325 K. The selective deposition of the PEDOT thin films using vapor-phase polymerization was accomplished with patterned $FeCl_3$ layers as templates. Microcontact printing was done to prepare patterned $FeCl_3$ on polyethyleneterephthalate (PET) substrates. The selective vapor-phase deposition is based on the fact that the PEDOT thin films are selectively deposited only on the regions exposing $FeCl_3$ of the PET substrates, because the EDOT monomer can be polymerized only in the presence of oxidants, such as $FeCl_3$, Fe($CIO_4$), and iron(II) salts of organic acids/inorganic acids containing organic radicals.

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