Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Rh2(Opiv)4-Catalyzed Reactions of Diazo Compound Derived from Meldrum's Acid and Styrenes. Efficient Synthesis of Cyclopropanes

  • Lee, Yong-Rok (School of Chemical Engineering and Technology, College of Engineering, Yeungnam University) ;
  • Choi, Jung-Hyun (School of Chemical Engineering and Technology, College of Engineering, Yeungnam University)
  • Published : 2006.04.20
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Abstract

The rhodium(II)-catalyzed reactions of diazo compound derived from Meldrum's acid with a variety of styrenes have been examined. These reactions provide a rapid route to the preparation of cyclopropanes with a variety of substituents on the benzene ring. The mechanistic pathway for the formation of these products has been also described in terms of a stepwise mechanism.

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References

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