Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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The Characterizations of Tape Casting for Low Temperature Sintered Microwave Ceramics Composite

저온소성 마이크로파 유전체 세라믹스 복합체의 Tape Casting특성

  • Lee, Woo-Suk (Department of Inorganic Materials Engineering, Pusan National University) ;
  • Kim, Chang-Hwan (Department of Inorganic Materials Engineering, Pusan National University) ;
  • Ha, Mun-Su (Electric and Magnetic Devices Group, KERI) ;
  • Jeong, Soon-Jong (Electric and Magnetic Devices Group, KERI) ;
  • Song, Jae-Sung (Electric and Magnetic Devices Group, KERI) ;
  • Ryu, Bong-Ki (Department of Inorganic Materials Engineering, Pusan National University)
  • 이우석 (부산대학교 무기재료공학과) ;
  • 김창환 (부산대학교 무기재료공학과) ;
  • 하문수 (한국전기연구원 전자기소자연구그룹) ;
  • 정순종 (한국전기연구원 전자기소자연구그룹) ;
  • 송재성 (한국전기연구원 전자기소자연구그룹) ;
  • 류봉기 (부산대학교 무기재료공학과)
  • Published : 2005.02.01
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Abstract

Sintering behavior of $BaO-Nd_{2}O_3-TiO_2$ with a Pb-based glassceramics frit were investigated in order to understand an effect of glassceramics as a low temperature sintering agent on dielectric ceramics. A green sheet form was fabricated through tape casting method with the glassceramic fut added $BaO-Nd_{2}O_3-TiO_2$. The dispersion properties, rheological properties and final density of dielectric composit slurry as a function of amount and composition of organic additives was examined. The dispersants' addition was effective in controlling dispersion of the ceramics in solution. The addition of excessive dispersant showed adverse effect on dispersion. The prepared slurries, containing ceramic : powders, glass-ceramics and various kinds of organic viechles, exhibited typical shear thinning behavior. The best properties of tape casting appeared powder to solvent ratio 65 : 35 and amount of the binder 6 wt$\%$ and plasticizer 3 wt$\%$. The viscosity of the slurry was 677 cps and green/sintered density in the tape was $3.3 g/cm^3,\;5.56 g/cm^3$ respectively.

마이크로파 유전체 세라믹스 $BaO-Nd_{2}O_3-TiO_{2}(BNT)$계 상용분말과 PbO-base의 결정화 유리프릿 복합체를 출발원료로 하여 테입 케스팅법으로 그린시트를 제초하기 위해 첨가유기물의 조성 변화에 따른 슬러리의 분산특성 및 유동특성 그리고 최종그린시트의 그린/소결밀도 변화를 연구하였다. 분산제량의 증가는 분산에 유효하였으나, 일정량 이상이 첨가되면 분산을 저해하는 요인으로 작용하였으며 복합체 분말에 1.75 wt$\%$의 fish oil을 첨가하였을 때 분산특성이 가장 우수하였다 준비된 모든 조성의 슬러리에서 의가소성거동(shear thinning)이 나타났고 파우더, 바인더 그리고 유기물의 전체 함량이 증가할수록 상대점도는 증가하는 경향을 나타내었다. 복합체 분말과 용매의 비율 65 : 35, 결합제는 6 wt$\%$, 가소제는 3 wt$\%$에서 테이프의 특성이 가장 우수하였다. 이때 슬러리의 점도는 677cps, 그린/소결밀도는 $3.3g/cm^3,\;5.56g/cm^3$로 각각 나타났다.

Keywords

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