Corrosion of Dental Au-Ag-Cu-Pd Alloys in 0.9 % Sodium Chloride Solution

  • 발행 : 2005.02.01

초록

Two Au-Ag-Cu-Pd dental casting alloys (Au:12% and 20%) used. The test solutions used 0.9 % NaCl solution (isotonic sodium chloride solution), 0.9 % NaCl solution containing 1 % lactic acid, and 0.9 % NaCl solution containing 1 % lactic acid and 0.1 mol $dm^{-3}$ $Na_2S$. The surface of two samples in three sample solutions was not natural discoloration during one year. The alloy containing 12 % gold was easily alloyed and the composition was uniform comparing with the alloy containing 20 % gold. The rest potentials have not a little effect after three months. The kinds of metals could not definitely from the oxidation and reduction waves of metal on the cyclic voltammograms. The dissolutions of gold and palladium were 12 % Au sample in the 0.9 % NaCl solution containing 1 % lactic acid and 0.1 mol $dm^{-3}$ $Na_{2}S$. The pH of solution had an affect on dissolution of copper, and sulfur ion had an affect on dissolution of silver. The copper dissolved amount from 20 % gold sample was about 26 times comparing with that of 12 % gold sample in the 0.9 % solution containing 1 % lactic acid. Corrosion products were silver chloride and copper chloride in NaCl solution, and silver sulfide and copper sulfide in NaCl solution containing $Na_{2}S$.

키워드

참고문헌

  1. Y. Takada, Zairyoto - Kankyo, 49, 454 (2000)
  2. L. Niemi and I. Holland, J. Den. Res., 63, 1014 (1984)
  3. B. Grosgogeat, M. Lissac, J. Brugirard, F. Dalard and L. Reclaru, J. Den. Res., 74, 938 (1995)
  4. M. Ohta, T. Shiraishi, M.. Nakagawa and S. Matsuya, J. Mat. Sci., 29, 2083 (1994)
  5. C. Mulders, M. Darwish and R. Holze, J. Oral. Rehabili, 23, 825 (1996)
  6. N. K. Sarker, D. W. Berzins, and A. Prasad, Den. Mater., 16, 374 (2000)
  7. D. W. Berzins, I. Kawashima, R. Graves, and N. K. Sarkar, Den. Mater., 16, 266 (2000)
  8. Z. Cai, S. G. Vermilyea, and W. A. Brantly: Dental Materials, 15, 202 (1999)
  9. J. Brugirard, R. Bargain, J. C. Dupuy, H. Mazille, and G. Monnier, J. Dent. Res. 52, 828 (1973)
  10. N. K. Sarkar, R. A. Fuys, and J. W. Stanford, J. Den. Res., 58, 1572 (1979)
  11. R. I. Holland, R. B. Jorgensen, and H. Hero, Den. Mater., 2, 143 (1986)
  12. R. I. Holland, Scand. J. Den. Res., 99, 75 (1991)
  13. C. Bessing, M. Bergman, and A. Thoren, Den. Mater., 3, 153 (1987)
  14. J. G. Gerstorfer and H. Weber, Den. Mater., 3, 289 (1987)
  15. R. I. Holland, Dent. Mater. 8, 241 (1992)
  16. Grosgogeat, M. Lissac, J. Brugirard, J. Dalard, and L. Reclaru, J. Den. Res., 74, 938 (1995)