Journal of Hydrogen and New Energy (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
권호 표지

Heat Treatment and Characterization of Serpentine for $CO_2$ Sequestration by Mineral Carbonation

이산화탄소 탄산염광물화용 사문석의 열처리 및 특성평가

  • Choi, Weon-Kyung (Department of Industrial Chemistry, Dankook University) ;
  • Moon, Seung-Hyun (Department of Industrial Chemistry, Dankook University) ;
  • Cho, Tae-Hwan (Department of Industrial Chemistry, Dankook University) ;
  • Lee, Jae-Keun (Korea Laboratory of Environmental and Structural Engineering, Korea Electric Power Research Institute)
  • 최원경 (단국대학교 공업화학과) ;
  • 문승현 (단국대학교 공업화학과) ;
  • 조태환 (단국대학교 공업화학과) ;
  • 이재근 (한전 전력연구원, 구조연구실)
  • Published : 2005.03.15
Download PDF
⟨ Previous Next ⟩

Abstract

The heat treatment of serpentines for mineral carbonation was studied systematically. Crystallographic, spectroscopic and thermochemical properties were investigated for serpentines before and after heat treatment. Drastic weight loss due to the removal of hydroxy groupe(-OH) occupied in serpentine crystalline was revealed after heat treatment. In XPS results, MgO was founded at heat treated serpentine powders while Mg(OH) was observed at untreated serpentine powders. Metallic oxides originated from serpentine ingredients were regenerated by heat treatment.

Keywords

References

  1. C. Schmidt, S. Klara and R. Srivastava, 'DOE Carbon Sequestration Program', US Department of Energy. Proceeding of the Electric Utilities Environmental Conference 2002, Tucson, Arizona
  2. E.Bryant, 'Climate process and change', Cambridge, UK: Cambridge University Press, 1997. p. 209
  3. C. Jepma and M. Munasinghe. 'Climate Change Policy', New York, NY: Cambridge University Press, 1998. p. 331
  4. R. Bajura, 'The role of carbon dioxide sequestration in the long term energy future', In: Fifth International Greenhouse Gas Technologies Conference, Cairns, Australia, Collingwood. VIC, AU: CSIRO Publishing, 2001. p. 52
  5. R. Pierce, 'Greenhouse gas mitigation technologies, an overview of the $CO_2$ capture, storage and future activities of the lEA Greenhouse Gas R&D programme', Energy Conversion and Management, Vol. 37, 1996, p. 665 https://doi.org/10.1016/0196-8904(95)00237-5
  6. P. Freund and W. Ormerod, 'Progress toward storage of carbon dioxide Energy Conversion and Management', Vol. 38, 1997, p. S199.4
  7. M. Peter, 'Impacts on the marine environment from direct and indirect ocean storage of $CO_2$ Waste Management', Vol. 17, 1998, p. 323 https://doi.org/10.1016/S0956-053X(97)10043-5
  8. K. Cole, P. Freund and W. G. Ormerod, 'Predicting future variability of dissolved inorganic carbon in the ocean Fuel and Energy', Vol. 37, 1996, p. 145
  9. M. Holtz, P. Nance and R. Finley, 'Reduction of greenhouse gas emissions through $CO_2$ EOR in Texas', Environ Geosci 2001, p. 99
  10. H. Koide and K. Yamazaki. 'Subsurface $CO_2$ disposal with enhanced gas recovery and biochemical carbon recycling', Environ Geosci, 2001, p. 24
  11. K. Lackner, D. Butt and C. Wendt, 'Progress on binding $CO_2$ ill mineral substrates,' Energy Convers Manage, Vol. 38, 1997, p. 259 https://doi.org/10.1016/S0196-8904(96)00279-8
  12. K. Lackner, C. Wendt, D. Butt, E. Joyce and D. Sharp, 'Carbon dioxide disposal in carbonate minerals', Energy, Vol. 20, 1995, p. 1153 https://doi.org/10.1016/0360-5442(95)00071-N
  13. R. Schulze, M. Hill, R. Field, P. Papin, R.Hanrahan and D. Byler, 'Characterization of carbonated serpentine using XPS and TEM', Energy Conversion and Management, Vol. 45, 2004, p. 3169 https://doi.org/10.1016/j.enconman.2004.02.003
  14. J. Post and L. Borer, 'High-resolution infrared spectra, physical properties, and micromorphology of serpentines', Applied Clay Science, Vol. 16, 2000, p. 73 https://doi.org/10.1016/S0169-1317(99)00047-2
  15. J. Moulder, W. Stickle, P. Sobol and K. Bomben. Handbook of X-ray photoelectron spectroscopy. Eden Prairie Minnesota: Perkin. Elmer; 1992