A study for the recovery molybdenum from the dissolved liquid of Mo. with a clean technology

몰리브덴 용해액에서 금속의 몰리브덴회수에 대한 청정기술에 관한 연구

  • Hong Jong-Soon (Department of Environmental Health, Dongnam Health College.)
  • 홍종순 (동남보건대학 환경보전과)
  • Published : 2005.03.01

Abstract

The process of reusing the treated water generated during this process and that of recovery of molybdenum from the excessive water were studied. The results were as follows. Molybdenum recollection 1. Reusing processing water generated after dissolving process on FL/20 type, the following were the remaining Mo.'s weights after the 1st, 2nd, 3rd, 4th, 5th, & 6th dissolutions respectively. 1) The result of measuring the quantity of Mo. in processing water(the 1st solving water) generated after the 1st dissolving Mo. process was $369g/\ell$ 2) The result of measuring the quantity of Mo. in processing water(the 2nd solving water) generated after the 1st dissolving Mo. process reusing the 1st solving water was $627.3g/\ell$ 3) The result of measuring the quantity of Mo. in processing water(the 3rd solving water) generated after the dissolving Mo. process reusing the 2nd solving water was $808.11g/\ell$ 4) The result of measuring the quantity of Mo. in processing water(the 4th solving water) generated after the dissolving Mo. process reusing the 3rd solving water was $934.68g/\ell$ 5) The result of measuring the quantity of Mo. in processing water(the 5th solving water) generated after the dissolving Mo. process reusing the 4th solving water was $1023.27g/\ell$ 6) The result of measuring the quantity of Mo. in processing water(the 6th solving water) generated after the dissolving Mo. process reusing the 5th solving water was $1085.29g/\ell$ 2. The followings were the results of recollectings Mo. in processing water respectively generated after dissolving Mo. to produce complete goods df FL/20 type filament. 1) the percentage of recollecting Mo. in the 1st solving water was $93.0\%$ 2) the percentage of recollecting Mo. in the 2nd solving water was $94.5\%$ 3) the percentage of recollecting Mo. in the 3rd solving water was $95.5\%$ 4) the percentage of recollecting Mo. in the 4th solving water was $96.0\%$ 5) the percentage of recollecting Mo. in the 5th solving water was $96.2\%$ 6) the percentage of recollecting Mo. in the 6th solving water was $96.4\%$ 3. The followings were the results of analyzing, with ICP, holding quantities of Mo. in the 6 processing waters to produce FL/20 type filament after passing a 3 staged solid-liquid separator through, dehydrating and drying for more than 3 hours in a dryer to recollect solving Mo. in them 1) the Mo. holding percentage in the 1st solving water was $76.6\%$ 2) the Mo. holding percentage in the 2nd solving water was $76.6\%$ 3) the Mo. holding percentage in the 3rd solving water was $76.6\%$ 4) the Mo. holding percentage in the 4th solving water was $76.6\%$ 5) the Mo. holding percentage in the 5th solving water was $76.6\%$ 6) the Mo. holding percentage in the 6th solving water was $76.6\%$ It was noted that with the number of times the recollecting Mo. percentage become higher, and in spite of much recollecting, without any large effect on the goods the solving water could be reused as the processing water. Because the collected Mo. holding percentages were more than $76\%$, it is considered they are very good one than Chinese Mo. ores with $50\%$ degrees of purity, worthy of recollecting Mo.

Keywords

References

  1. 권창용, 수소크롬(VI)산이온에 의한 몰리브덴(IV) 및 (V)의 옥살산 착물의 산화반응, (대구대학교 대학원, 1985.12.)
  2. 권찬우, 산성수용액에서 아쿠아옥소몰리브덴늄(V)착물의 이합화반응속도와 그 메카니즘, (대구대학교 대학원, 1986. 7.)
  3. 김창수. 몰리브덴(V)의 피리딘계 착물합성과 그 성질, (대구대학교 대학원, 1981.12)
  4. 이중호, 아쿠아옥소 몰리브텐(IV, V) 착물과 티오시안산 이온과의 반응속도와 메카니즘, (대구대학교 대학원, 1987. 6.)
  5. 안세진, 디티오카바마토디옥소 몰리브덴(VI)착물과 산소이동 반응에 대한속도와 메카니즘, (대구대학교 대학원, 1989. 6)
  6. 이시가와 미사오, 관구용코일 필라멘트의 몰리브덴심선의 용해방법, (대한민국 특허청, 특허공보 제528호, 공고번호 80-1407, 1980)
  7. 강원준, 오존, 과산화수소, UV를 이용한 고급 산화처리 공정의 kinetic에 관한 연구, (J. of KSEE Vol. 15. No. 2, 1993), p. 501-510