Bulletin of the Korean Chemical Society

  • 제26권10호
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  • Pages.1512-1514
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Selective Hydrogenation of 1,3-Butadiene over Supported Nickel Catalyst Obtained from Nickel-Zirconia Solid Solution

  • Chang, Jong-San (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Ryu, Jae-Oak (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Lee, Jong-Min (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Park, Sang-Eon (Department of Chemistry, Inha University) ;
  • Hong, Do-Young (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Jhung, Sung-Hwa (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT))
  • 발행 : 2005.10.20
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초록

Catalytic properties of Ni-Zr$O_2$ catalysts prepared by coprecipitation have been studied for the gas-phase hydrogenation of 1,3-butadiene to butenes. The coprecipitation method led to the solid solution of Ni-Zr$O_2$, which contains highly resistant Ni species to thermal reduction with H2. Nickel species of the solid solution were highly dispersed in the ZrO2 lattice, so that the reduced catalysts were selective for hydrogenation of 1,3-butadiene to butenes (99.9%) even in the presence of 1-butene.

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참고문헌

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피인용 문헌

  1. Chemical Bonding Nature and Mesoporous Structure of Nickel Intercalated Montmorillonite Clay vol.27, pp.9, 2005, https://doi.org/10.5012/bkcs.2006.27.9.1323