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NO REDUCTION PROPERTY OF Pt-V2O5-WO3/TiO2 CATALYST SUPPORTED ON PRD-66 CERAMIC FILTER

  • Kim, Young-Ae (Department of Chemical & Biological Engineering/ERI, Gyeongsang National University) ;
  • Choi, Joo-Hong (Department of Chemical & Biological Engineering/ERI, Gyeongsang National University) ;
  • Bak, Young-Cheol (Department of Chemical & Biological Engineering/ERI, Gyeongsang National University)
  • Published : 2005.10.31

Abstract

The effect of Pt addition over $V_2O_5-WO_3/TiO_2$ catalyst supported on PRO-66 was investigated for NO reduction in order to develop the catalytic filter working at low temperature. Catalytic filters, $Pt-V_2O_5-WO_3/TiO_2/PRD$, were prepared by co-impregnation of Pt, V, and W precursors on $TiO_2$-coated ceramic filter named PRD (PRD-66). Titania was coated onto the pore surface of the ceramic filter using a vacuum aided-dip coating method. The Pt-loaded catalytic filter shifted the optimum working temperature from $260-320^{\circ}C$(for the catalytic filter without Pt addition) to $190-240^{\circ}C$, reducing 700 ppm NO to achieve the $N_x$ slip concentration($N_x\;=\;NO+N_2O+NO_2+NH_3$) less than 20 ppm at the face velocity of 2 cm/s. $Pt-V_2O_5-WO_3/TiO_2$ supported on PRD showed the similar catalytic activity for NO reduction with that supported on SiC filter as reported in a previous study, which implies the ceramic filter itself has no considerable interaction for the catalytic activity.

Keywords

References

  1. Choi, J. H., Kim, S. K., Ha, S. J., and Bak, Y. C., '$Pt-V_20_5-WO_3/TiO_2$ Catalysts Supported on SiC Filter for NO Reduction at Low Temperature,' Korean J. Chem. Eng., 22(6) (2005)
  2. Amiridis, M. D., Wachs, I. E., and Jehng, J. M., 'Reactivity of the $V_20_5$ catalysts for the Selective Catalytic Reduction of NO by $NH_3$,' J. Catal., 161, 247 (1996)
  3. Bosch, H. and Janssen, F., 'Catalytic reduction of nitrogen oxides, A review on the fundamentals and technology,' Catal. Today, 2, 369 (1988)
  4. Ham, S. W., Nam, I. S., and Kim, Y. G., 'Activity and Durability of Iron-exchanged Mordenite-type Zeolite Catalyst for the Reduction of NO by $NH_3$,' Korean J. of Chem. Eng., 17(3), 318 (2000)
  5. Kim, M. H., Nam, I-S., and Kim, Y. G., 'Reaction Intermediate over Mordenite-Type Zeolite Catalysts for NO Reduction by Hydrocarbons,' Korean J. Chem. Eng., 16(1), 139 (1999)
  6. Lee, H-T. and Rhee, H-K., 'Steam Tolerance of Fe/ZSM-5 Catalyst for the Selective Catalyitic Reduction of NO,' Korean J. Chem. Eng., 20(1), 574 (2002)
  7. Nam, I. S., 'A Catalytic Process for the Reduction of NOx from Stationary Sources,' Catalysis, 11(1),5 (1995)
  8. Forzatti, P. and Lietti, L., 'Recent advances in De-$NO_x$ing catalysis for stationary applications,' Heterog. Chem. Rev., 3(1), 33 (1996)
  9. Busca, G., Lietti, L., Ramis, G. and Berti, F., 'Chemical and mechanistic aspects of the selective catalytic reduction of $NO_x$ by ammonia over oxide catalysts: A review,' Applied Catal. B, Environ., 18, 1 (1998)
  10. Alemany, L. J., Lietti, L., Ferlazzo, N., Forzatti, P., G., Busca, Giamello, E., and Bregani, F., 'Reactivity and physicochemical characterization of $V_20_5-WO_3/TiO_2$ De-$NO_x$ catalysts,' J. of Catalysis, 155, 117 (1995) https://doi.org/10.1006/jcat.1995.1193
  11. Choi, J. H., Kim, S. K., Ha, S. J. and Bak, Y. C., 'The Preparation of $V_2O_5/TiO_2$ Catalyst Supported on the Ceramic Candle for Selective Reduction of NO,' Korean J. Chem. Eng., 18(4), 456 (2001) https://doi.org/10.1007/BF02707191
  12. Choi, J. H., Kim, S. K., and Y. C., 'The Reactivity of $V_2O_5-WO_3-TiO_2$ Catalyst Supported on a Ceramic Filter Candle for Selective Reduction of NO,' Korean J. Chem. Eng., 18(5), 719 (2001) https://doi.org/10.1007/BF02706392
  13. AlliedSignal, 'Preliminary Engineering Data,' AlliedSignal Composites Inc., P.O. Box 9559, Newark, DE 19714-9559 (1999)
  14. Zhu, Z., Liu, Z., Niu, H., and Liu, S., 'Promoting Effect of $SO_2$ on Activated Carbon-Supported Vanadia Catalyst for NO Reduction by $NH_3$ at Low Temperatures,' J. Catal., 187, 245 (1999)
  15. Linsebigler, A. L., Lu, G. and Yates, J. T. Jr., 'Photocatalysis on $TiO_2$ Surface: Principles, Mechanisms, and Selected Results,' Chem. Rev., 95, 735 (1995)
  16. Paganini, M. C., Acqua, L. D., Giamello, E. G., Lietti, L., Foratti, P., and Busca, G., 'An EPR study of the Surface Chemistry of the $V_2O_5-WO_3/TiO_2$ Catalyst: Redox Behaviour and State of V(IV),' J. Catal., 166, 195 (1997) https://doi.org/10.1006/jcat.1997.1492
  17. Siemon, U., Bahnemann, D., Testa, J. J., Rodriguez, D., Litter, M. I., and Bruno, N., 'Heterogeneous photo catalytic reactions comparing $TiO_2$ and $pt/TiO_2$,' J. of Photochemistry and Photobiology A: Chemistry, 148, 247 (2002)
  18. Sanchez, E. and Lopez, T., 'Effect of preparation method on the band gap of titania and platinum-titania sol-gel materials,' Mat. Lett., 25, 271 (1995)
  19. Jung, S. M. and Grange, P., Investigation of the promotional effect of $V_2O_5$ on the SCR reaction and its mechanism on hybrid catalyst with $V_2O_5$ and $TiO_2-SO_4^{2-}$ catalysts,' Applied Catalysis B: Environ., 36, 325 (2002) https://doi.org/10.1016/S0926-3373(01)00314-9
  20. Van den Broek, A.C.M., van Grondelle, J., and van Santen, R.A., 'Determination of Sulface Coverage of Catalysts,' J. of Catlysis, 185, 297 (1999)
  21. Sobczyk, D. P., van Grondelle, J., Thune, P. C., Kieft, I. E., de Jong, A. M., and van Santen, R. A., 'Low-temperature ammonia oxidation on platinum sponge studied with positron emission profiling,' J. Catal., 225, 466 (2004)
  22. Taguchi, J. and Okuhara, T., 'Selective oxidative decomposition of ammonia in neutral water to nitrogen over titania-supported platinum or palladium catalyst,' Applied Catal. A: General, 194-195, 89 (2000)