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Hydrophilic Effect of the Polyimide by Atmospheric Low-temperature Plasma Treatment

대기압 저온 플라즈마 처리에 의한 폴리이미드의 친수화 효과

  • 조중희 ((주)창조 엔지니어링) ;
  • 강방권 ((주)창조 엔지니어링) ;
  • 김경수 ((주)창조 엔지니어링) ;
  • 최병규 (강릉대학교 금속재료공학과) ;
  • 김세훈 (강릉대학교 세라믹공학과) ;
  • 최원열 (강릉대학교 금속재료공학과)
  • Published : 2005.02.01

Abstract

Atmospheric low-temperature plasma was produced using dielectric barrier discharge (DBD) plate-type plasma reactor and high frequency of 13.56 Hz. The surfaces of polyimide films for insulating and packaging materials were treated by the atmospheric low-temperature plasma. The contact angle of 67$^{\circ}$ was observed before the plasma treatment. The contact angle was decreased with deceasing the velocity of plasma treatment. In case of oxygen content of 0.2 %, electrode gap of 2 mm, the velocity of plasma treatment of 20 mm/sec, and input power of 400 W, the minimum contact angle of 13$^{\circ}$ was observed. The chemical characteristics of polyimide film after the plama treatment were investigated using X-ray photoelectron spectroscopy (XPS), and new carboxyl group bond was observed. The surfaces of polyimide films were changed into hydrophilic by the atmospheric low-temperature plasma. The polyimide films having hydrophilic surface will be very useful as a packaging and insulating materials in electronic devices.

Keywords

References

  1. S. Kanazawa, M. Kogoma, T. Moriwaki, and S. Okazaki, 'Stable glow plasma at atmospheric pressure', J. Phys. D: Appl. Phys., Vol. 21, p. 838, 1988
  2. Y. Tsuchiya, K. Akutu, and A. Iwata, 'Surface modification of polymeric materials by atmospheric plasma treatment', Progress in Organic Coatings, Vol. 34, p. 100, 1998
  3. E. Kunhardt, 'Generation of large-volume, atmospheric-pressure, nonequilibrium plasma', IEEE Trans. Plasma Sci., Vol. 28, p. 189, 2000
  4. S. Moon, W. Choe, and B. Kang, 'A uniform glow discharge plasma source at atmospheric pressure', Applied Physics Letters, Vol. 84, No. 2, p. 188, 2004
  5. Y. Guo and F. Hong, 'Radio-frequency microdischarge arrays for large-area cold atmospheric plasma generation', Applied Physics Letters, Vol. 82, No. 3, p. 337, 2003
  6. J. Moulder, W. Stickle, P. Sobol, and K. Bornben: Handbook of X -ray Photoelectron Spectroscopy, Physical Electronics, Inc., United States of America, 1995
  7. N. Cui and N. Brown, 'Modification of the surface properties of a polypropylene (PP) film using an air dielectric barrier discharge plasma', Applied Surface Science, Vol. 189, p. 31, 2002
  8. M. Kim, D. Song, H. Shin, S. Baeg, G. Kim, J. Boo, J. Han, and S. Yang, 'Surface modification for hydrophilic property of stainless steel treated by atmospheric-pressure plasma jet', Surface and Coatings Technol., Vol. 171, p. 312, 2003

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