한국재료학회지 (Korean Journal of Materials Research)

  • 제15권12호
  • /
  • Pages.802-808
  • /
  • 2005
  • /
  • 1225-0562(pISSN)
  • /
  • 2287-7258(eISSN)
한국재료학회 (Materials Research Society of Korea)
권호 표지
DOI QR코드

DOI QR Code

게터용 Zr57V36Fe7 합금의 수소 흡수특성에 미치는 비정질화의 영향

The Effects of Amorphization on Hydrogen Absorption Properties of Zr57V36Fe7 Getter alloy

  • 박제신 (한국지질자원연구원 자원활용소재연구부 소재개발연구실) ;
  • 서창열 (한국지질자원연구원 자원활용소재연구부 소재개발연구실) ;
  • 김원백 (한국지질자원연구원 자원활용소재연구부 소재개발연구실)
  • Park Je-Shin (Minerals and materials processing Division, Materials Development Group, Korea Institute of Geoscience, Mining and Materials) ;
  • Suh Chang-Youl (Minerals and materials processing Division, Materials Development Group, Korea Institute of Geoscience, Mining and Materials) ;
  • Kim Won-Baek (Minerals and materials processing Division, Materials Development Group, Korea Institute of Geoscience, Mining and Materials)
  • 발행 : 2005.12.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The hydrogen sorption speeds of $Zr_{57}V_{36}Fe_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature $Zr_{57}V_{36}Fe_7$ amorphous alloy was prepared by ball milling. The amorphous alloy was crystallized through two stages. Initially, $\alpha-Zr$ solid solution was appeared from the amorphous phase. Two cubic Laves compounds were precipitated afterwards from the remained amorphous and from excessively saturated solid solution at higher temperature. The hydrogen sorption speed of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption speed of partially crystallized alloy was explained in terms of surface oxygen stability which has been known to retard the activation of amorphous alloys. The retardation could be reduce by crystallization process resulting in the observed increase in sorption property.

키워드

참고문헌

  1. C. Benvenuti, II European Vacuum Conference, 21 (1990)
  2. P. della Porta, Vacuum 47(6-8), 771 (1996) https://doi.org/10.1016/0042-207X(96)00064-4
  3. E. Schaschel, Metal Powder Report, 46(12), 30 (1991) https://doi.org/10.1016/0026-0657(91)91661-O
  4. K. Derbyshire, Solid State Technol., 37, 55 (1994) https://doi.org/10.1016/0038-1101(94)90104-X
  5. Kenji Ichimura, Naoya Inoue, Kuniaki Watanabe and Toyosaburo Takeuchi, J. Vac. Sci. Technol., A2 (3), 1341 (1984) https://doi.org/10.1116/1.572406
  6. C. Benvenuti and P. Chiggiato., J. Vac. Sci. Technol., A14 (6), 1341 (1996) https://doi.org/10.1116/1.589093
  7. B. Ferrario, A. Figini and M. Borghil, Vacuum, 35, 13 (1985) https://doi.org/10.1016/0042-207X(85)90070-3
  8. Surya Parkash Garg, Earl A, Gulbransen and P Vijendranl, Vacuum, 40, 275 (1990) https://doi.org/10.1016/0042-207X(90)90043-X
  9. C. Benvenuti, Vacuum, 44(5-7), 511 (1993) https://doi.org/10.1016/0042-207X(93)90084-N
  10. H. F. Dylla, J. Cecchiard M. DIrickson, J. Vac. Sci. Technol., 18 (3), 1111 (1931)
  11. C. Boffito, B. Ferrario P. Della Porta and L. Rosail, J. Vac. Sci. Technol., 18 (3), 1111 (1981) https://doi.org/10.1116/1.570850
  12. R. J. Knize, J. L. Cecchi and H. F. Dylla, J. Vac. Sci. Technol., 20, 1135 (1982) https://doi.org/10.1116/1.571588
  13. Kenji lchimura, Naoya Inoue, Kuniaki Watanabe and Toyosaburo Takeuchil, J. Nuclear Materials, 128, 876 (1984) https://doi.org/10.1016/0022-3115(84)90474-4
  14. J. S. Park, D. J. Lee, D. S. Kil and W. B. Kim, J. the Korean Society for Geosystem Engineering. 41 (6), 496 (2004)
  15. J. S. Park, C. Y. Suh and W. B. Kim, Korean J. of Materials Research, 15(6), 388 (2005) https://doi.org/10.3740/MRSK.2005.15.6.388
  16. Y. Iijima and K. Hirano, Eull. JIM 14 599 (1975)
  17. J. O. Strom-Olsen, Y. Zhao, D. H. Ryan, Y. Huai and R. W. Cochrane, J. Less-Common Met. 172-179, 922 (1991) https://doi.org/10.1016/S0022-5088(06)80338-3
  18. H. Wipf, Hydrogen in Metals, Vol. 3 springer, Chap. 3 (1997)
  19. D. Shaltiel, Less-Common Met. 73, 329 (1980) https://doi.org/10.1016/0022-5088(80)90326-4
  20. D. Richter, R. Hempelman and R. C. Bowman, Hydrogen in Intermetallic Compounds, Vol. 2, Springer, chap. 3 (1992)
  21. X. G. Li, T. Otahara, S. Takahashi, T. Shoji. H. M. Kimura and A. Inoue, J. of Alloys and Compounds, 297, 303 (2000) https://doi.org/10.1016/S0925-8388(99)00614-3
  22. K. Cheistmann, Surf. Sci. Rep. 9, 1 (1988) https://doi.org/10.1016/0167-5729(88)90009-X
  23. D. J. Lee, W. Kim, S. R. In, J. Y. Im and K. B. Kim, J. the Korean Vacuum Society, 14(1), 1 (2005)
  24. S. R. In, M. Y. Park and K. S. Jung, J. the Korean Vacuum Society, 13, 47 (2004)
  25. K. H. Chung, KRISS/IR-2003-097, 99 (2003)
  26. M. M. Gunter, D. Herein, R. Schumacher, G. Weinberg and R. Schogl, J. Vac. Sci. Technol., A16 (6), 3526 (1998) https://doi.org/10.1116/1.590490
  27. W. B. Kim, D. J. Lee, J. S. Park, C. Y. Suh and J. C. Lee, Korean J. of Materials Research, 15(2), 79 (2005) https://doi.org/10.3740/MRSK.2005.15.2.079
  28. B. Ferrario, Vacuum, 47(4) 363 (1996) https://doi.org/10.1016/0042-207X(95)00252-9
  29. W. V. Lampert, K. D. Rachocki, B. C. Lamartine and T. W. Haas, J. Vac. Sci. Technol. 18(3), 1121 (1981) https://doi.org/10.1116/1.570853