Korean Journal of Crystallography (한국결정학회지)

Korean Crystallographic Association (한국결정학회)
권호 표지

Absolute Configuration of Di-(2-Picolyl) sulfur Dichloro Zinc(II) with an Enantiomorphic Space Group $P4_12_12$

Enantiomorphic 공간군 $P4_12_12$을 갖는 Di-(2-Picolyl) sulfur Dichloro Zinc(II)의 Absolute Configuration

  • Choi Ki-Young (Department of Chemistry Education, Kongju National University) ;
  • Lee Han-Hyoung (Department of Chemistry Education, Kongju National University) ;
  • Kim Min-Hee (Department of Chemistry Education, Kongju National University) ;
  • Whang Min-Ah (Department of Chemistry Education, Kongju National University) ;
  • Kang Sang Ook (Department of Material Chemistry, Korea University) ;
  • Son Ho-Jin (Department of Material Chemistry, Korea University) ;
  • Son Ki-Chul (Department of Material Chemistry, Korea University) ;
  • Han Won-Sik (Department of Material Chemistry, Korea University) ;
  • Suh Il-Hwan (Department of Material Chemistry, Korea University)
  • 최기영 (공주대학교 화학교육과) ;
  • 이한형 (공주대학교 화학교육과) ;
  • 김민희 (공주대학교 화학교육과) ;
  • 황민아 (공주대학교 화학교육과) ;
  • 강상욱 (고려대학교 자연과학대학 신소재화학과) ;
  • 손호진 (고려대학교 자연과학대학 신소재화학과) ;
  • 손기철 (고려대학교 자연과학대학 신소재화학과) ;
  • 한원식 (고려대학교 자연과학대학 신소재화학과) ;
  • 서일환 (고려대학교 자연과학대학 신소재화학과)
  • Published : 2005.06.01
Download PDF
⟨ Previous Next ⟩

Abstract

The crystal structure of an enantiomeric compound di-(2-picolyl)sulfur dichloro zinc(II), $C_{12}H_{12}N_2SCl_2Zn$, could be elucidated with two space groups $P4_12_12\;and\;P4_32_12$. However, its absolute configuration with the space group $P4_12_12$ was confirmed by means of the effect of anomalous dispersion.

거울상 이성질체인 di-(2-picolyl) sulfur dichloro Zinc(II), $C_{12}H_{12}N_2SCl_2Zn$의 결정구조가 두 개의 공간군 $P4_12_12\;과\;P4_32_12$로 밝혀질 수 있었다. 그러나 공간군 $P4_12_12$를 갖는 그의 absolute configuration이 anomalous dispersion의 효과에 의하여 확인되었다.

Keywords

References

  1. International Tables for Crystallography, Vol. A Edited by Theo Hahn (Kluwer Academic Publishers, pp. 21-22, 27-28, 358-359, 366-367 (1995)
  2. Bruker SMART (version 5.0) and SAINT-plus (Version 6.0). Bruker AXS Inc., Madison, Wisconsin, U.S.A. (1999)
  3. Sheldrick, G M., SHELX97. University of Goettingen, Germany (1997)
  4. Flack, H. D., Acta Cryst., A39, 876-881 (1983)
  5. Farrugia, L. J., J. Appl. Cryst. pp. 30. 565 (1997)