Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
권호 표지

Absorption Characteristics of Carbon Dioxide in Aqueous AMP Solution Adding HMDA

HMDA 첨가에 따른 AMP 수용액의 이산화탄소 흡수특성

  • Choi Won-Joon (Department of Environmental Engineering, Pusan National University) ;
  • Cho Ki-Chul (Department of Environmental Engineering, Pusan National University) ;
  • Oh Kwang-Joong (Department of Environmental Engineering, Pusan National University)
  • Published : 2005.12.01
Download PDF
⟨ Previous Next ⟩

Abstract

In this study, the possible use of HMDA (Hexamethylenediamine) as additive to enhance reaction between $CO_{2}$ and AMP (2-amino-2-methyl-1-propanol) which has higher absorption capacity than that of MEA (Monoethanolamine) was investigated. Also, the absorption capacity for $CO_{2}$ was compared with addition of HMDA, piperazine or MDEA (N-methyldiethanolamine) into $30\;wt\%$ AMP at $40^{circ}C$ and $CO_{2}$ partial pressure ranging from 0.5 to 120 kPa. Apparent rate constant ($K_{app}$) and absorption capacity with the addition of $5\∼20\;wt\%$ HMDA into AMP increased $214.2\∼276.3\%$ and $29.9\∼91.7\%$ than those of AMP alone. As a result, when $5\;wt\%$ HMDA added into AMP, the increasing rate of the absorption rate and the absorption capacity was found to be the highest. In addition, the absorption capacity increased $6.8\%,\;9.8\%,\;11.6\%$ with addition of MDEA, piperazine or HMDA respectively as compared to AMP alone at $CO_{2}$ partial pressure of 20 kPa. Consequently, HMDA as additive to improve absorption capacity of AMP was superior to other additives.

Keywords

References

  1. 양승만, 홍원희, 박승빈 (1995) 흡수법을 이용한 저에너지 $CO_2$회수 기술개발 연구. 통상산업부, 279pp
  2. 엄희문 (2003) 화력발전소에서 $CO_2$의 분리회수 및 전환기술의 Demo Plant 적용연구, 산업자원부, 41pp
  3. 오광중, 최원준, 이상섭, 조상원, 손병현 (2003) 알카놀아민류 흡수제를 이용한 $CO_2$와 $H_2S$ 혼합가스의 흡수능에 관한 연구, 대한환경공학회지, 25(4), 465-471
  4. 이재정, 오광중, 손병현 (1997) AMP(2-amino-2-methyl-1-propanol)수용액에서 piperaxine 첨가시 $CO_2$ 흡수에 미치는 영향, 대한환경공학회지, 19(7), 871-880
  5. 조승헌, 김석철, Dellink Rob, 장현정, 전해원 (2003) 기후변화 영향분석모델: 환경편익을 고려한 온실가스 저감에 따른 경제성 분석, 한국환경정책 . 평가연구원, 134 pp
  6. Bishnoi, S. and G.T. Rochelle (2000) Absorption of carbon dioxide into aqueous piperazine: reaction kinetics, mass transfer and solubility, Chem. Eng. Sci., 55, 5531-5543 https://doi.org/10.1016/S0009-2509(00)00182-2
  7. Rebolledo-Libreros, M.E. and A. Trejo(2004) Gas solubility of $CO_2$in aqueous solutions of N-methyldiethano-lamine and diethanolamine with 2-amino-2-methyl-1-propanol, Fluid Phase Equilibria, 218, 261 -267 https://doi.org/10.1016/j.fluid.2003.12.012
  8. Saha, A.K. and S.S. Bandyopadhyay (1995) Kinetics of absorption of $CO_2$ into aqueous solutions of 2-amino-2-methyl-1 -propanol, Chem. Eng. Sci., 50(22), 3587-3598 https://doi.org/10.1016/0009-2509(95)00187-A
  9. Sartori, G. and D.W. Savage (1983) Sterically hindered amine for $CO_2$ removal from gases, Ind. Eng. Chem. Fundam, 22, 239-249 https://doi.org/10.1021/i100010a016
  10. Sun, W.C., C.B. Yong, and M.H. Li (2005) Kinetics of the absorption carbon dioxide into mixed aqueous solutions of 2-amino-2-methyl-l -propanol and piperazine, Chem. Eng. Sci., 60, 503-516 https://doi.org/10.1016/j.ces.2004.08.012
  11. Xiao, J., C.W. Li, and M.H. Li (2000) Kinetics of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1-propanol+ monoethanola-mine, Chem. Eng. Sci., 55, 161-175 https://doi.org/10.1016/S0009-2509(99)00303-6
  12. Xu, S., Y.W. Wang, F.D. Otto, and A.E. Mather (1996) Kinetics of the reaction of carbon dioxide with 2-amino-2-methyl-1-propanol solutions, Chem. Eng. Sci., 51(6), 841-850 https://doi.org/10.1016/0009-2509(95)00327-4