Prediction of Membrane Fouling Index by Using Happel Cell Model

Happel Cell 모델을 이용한 막오염 지수 예측

  • 박찬혁 (고려대학교 공과대학 사회환경시스템공학과) ;
  • 김하나 (고려대학교 공과대학 사회환경시스템공학과) ;
  • 홍승관 (고려대학교 공과대학 사회환경시스템공학과)
  • Received : 2005.07.25
  • Accepted : 2005.09.20
  • Published : 2005.10.15

Abstract

Membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI) is an important parameter in design of the integrated RO/NF membrane processes for drinking water treatment. In this study, the effect of particle, membrane and feed water characteristics on membrane fouling index were investigated systematically. Higher fouling index values were observed when filtering suspensions with smaller particle size and higher feed particle concentration. Larger membrane resistance due to smaller pore size resulted in an increased membrane fouling index. The variations of feed water hardness and TDS concentrations did not show any impact on fouling index, suggesting that there were no significant colloidal interactions among particles and thus the porosity of particle cake layer accumulated on the membrane surface could be assumed to be 0.36 according to random packing density. Based on the experimental observations, fundamental membrane fouling index model was developed using Happel Cell. The effect of primary model parameters including particle size ($a_p$), particle concentration ($C_o$), membrane resistance ($R_m$), were accurately assessed without any fitting parameters, and the prediction of membrane fouling index such as MFI exhibited very good agreement with the experimental results.

Keywords

Acknowledgement

Grant : 상업용 FRM(Fouling Resistant Membrane)의 비교 평가 및 Fouling Mechanism 규명

Supported by : (주)새한

References

  1. Boerlage, Siobhan F.E., Kennedy, M.D., Dickson, M.R., ElHodali, Dima E.Y., Schippers. J.C. (2002) The Modified Fouling Index using Ultrafiltration Membranes (MFI-UF): Characterization, Filtration Mechanisms and Proposed Reference Membrane, Journal of Membrane Science, 197, pp. 1-21 https://doi.org/10.1016/S0376-7388(01)00618-4
  2. Boerlage, Siobhan F.E., Kennedy, M., Aniye, M.P., Schippers, J.C (2003) Applications of the MFI-UF to Measure and Predict Particulate Fouling in RO Systems, Journal of Membrane Science, 220, pp. 97-116 https://doi.org/10.1016/S0376-7388(03)00222-9
  3. Brauns, E., Van Hoof, E., Molenberghs, B., Dotremont, C, Doyen, W., Leysen, R. (2002) A New Method of Measuring and Presenting the Membrane Fouling Potential, Desalination, 150(1), pp. 31-43 https://doi.org/10.1016/S0011-9164(02)00927-X
  4. Hong, S., Faibish, Ron S., Elimelech, M. (1997) Kinetics of Permeate Flux Decline in Crossflow Membrane Filtration of Colloidal Suspensions, Journal of Colloid and Interface Science, 196, pp. 267-277 https://doi.org/10.1006/jcis.1997.5209
  5. Lyonnaise des Eaux. (1996) Water Treatment Membrane Processes, pp. 9.16-9.29, AWWARF, McGraw-Hill, New York
  6. Schippers, J.C., Verdouw, J. (1980) The Modified Fouling Index, a Method of Determining the Fouling Chracteristics of Water, Desalination, 32, pp. 137-148 https://doi.org/10.1016/S0011-9164(00)86014-2
  7. Song, L., Elimelech, M. (1995) Theory of Concentration Polarization in Crossflow Filtration, Journal of the Chemical Society Faraday Transactions, 91, pp. 3389-3398 https://doi.org/10.1039/ft9959103389
  8. Standard Test Method for Silt Density Index (SDD of Water, ASTM D4189-95, pp. 395-397
  9. Vrouwenvelder, J.S., Kappelhof, J.W.N.M., Heijman, S.G.J., Schippers, J.C, Kooij, D. (2003) Tools for Fouling Diagnosis of NF and RO Membranes and Assessment of the Fouling Potential of Feed Water, Desalination, 157(1-3), pp.361-365 https://doi.org/10.1016/S0011-9164(03)00417-X
  10. Wijmans, J. G., Nakao, S., van den Berg, J.W.A., (1985) Hydrodynamic Resistance of Concentration Polarization Boundary Layers in Ultrafiltration, Journal of Membrane Science, 22, pp.117-135 https://doi.org/10.1016/S0376-7388(00)80534-7