DOI QR코드

DOI QR Code

Electrochemical Characteristics of Hybrid Capacitor and Pulse Performance of Hybrid Capacitor / Li-ion Battery

Hybrid Capacitor의 전기화학적 특성 및 Hybrid Capacitor / Li-ion Battery의 펄스 방전 특성

  • 이선영 (한국전기연구원 전지연구그룹) ;
  • 김익준 (한국전기연구원 전지연구그룹) ;
  • 문성인 (한국전기연구원 전지연구그룹) ;
  • 김현수 (한국전기연구원 전지연구그룹)
  • Published : 2005.12.01

Abstract

In this study, we have prepared, as the pluse power source, a commercially supplied Li-ion battery with a capacity of 700 mAh and AC resistivity of 60 md at 1 kHz and nonaqeous asymmetric hybrid capacitor composed of an activated carbon cathode and MCMB anode, and have examined the electrochemical characteristics of hybrid capacitor and the pulse performances of parallel connected hybrid capacitor/Li-ion battery source. The nonaqueous asymmetric hybrid capacitors constituted with each stack number of pairs composed of the cathode, the porous separator and the anode electrode were housed in Al-laminated film cell. The 10 stacked hybrid capacitor, which was charged and discharged at a constant current at 0.25 $mA/cm^2$ between 3 and 4.3 V, has exhibited the capacitance of 108F and the lowest equivalent series resistance was 32 $m{\Omega}$ at 1 kHz. On the other hand, the enhanced run time of Li-ion battery assisted by the hybrid capacitor was obtained with increasing of current density and pulse width in Pulse mode. The best improvement, $84\;\%$ for hybrid capacitor/Li-ion battery was obtained in the condition of a 7C-rate pulse (100 msec)/0.5C-rate standby/$10\;\%$ duty cycle.

Keywords

References

  1. S. H. Choi, J. S. Kim, and Y. S. Yoon, 'Fabrication and characterization of a $LiCoO_{2}$ battery-supercapacitor combination for a high-pulse power system', J. Power sources, Vol. 138, p. 360, 2004
  2. T. R. Jow, J. P. Zheng, and S. P. Ding, 'Pulse performance of a Li -ion battery assisted by on electrochemical capacitor based on amorphous hydrous ruthenium oxide', The 7th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, 1997
  3. C. E. Hollan, J. W. Weidner, R. A. Dougal, and R. E. White, 'Experimental characterization of hybrid power systems under pulse current loads', J. Power sources, Voi. 109, p. 32, 2002
  4. G. Sikha and M. B. N. Popov, 'Performance optimization of a battery-capacitor hybrid system', J. Power sources, Vol. 134, p, 130, 2004
  5. A. D. Pasquier, I. Plitz, S. Menocal, and G. Amatucci, 'A comparative study of Li-ion battery, supercapacitor and nonaqueous asymmetric hybrid devices for automotive applications', J. Power sources, Vol. 115, p. 171, 2003
  6. 김익준, 이선영, 도칠훈, 문성인, '전기이중층 커패시터의 특성에 미치는 혼성 도전재의 영향', 전기전자재료학회논문지, 17권, 1호, p. 107, 2004
  7. 김익준, 이선영, 문성인, EDLC용 CMC+PTFE 혼합바인더 전극의 전기적, 기계적 특성', 전기전자재료학회논문지, 17권, 10호, p. 1079, 2004
  8. G. G. amatucci, F. Badway, A. D. Pasquier, and T. Zheng, 'An asymmetric hybrid nonaqueous energy storage cell', J. Electrochem. Soc., Vol. 148 p. A930, 2001