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Phosphorus Fractionations in Sediment of Mankyung and Dongjin River

만경강과 동진강 주요 지점 하천토사 중 형태별 인의 함량

  • Han, Kang-Wan (Department of Agricultural Chemistry, Chonbuk National University) ;
  • Son, Jae-Kwon (Department of Agricultural Engineering, Chonbuk National University) ;
  • Cho, Jae-Young (Department of Agricultural Chemistry, Chonbuk National University) ;
  • Kim, Hyo-Kyeong (Division of Pesticide Safety, National Institute of Agricultural Science and Technology, RDA) ;
  • Hwang, Seon-Ah (Department of Agricultural Chemistry, Chonbuk National University)
  • Published : 2005.12.31

Abstract

Sediments of Mankyung and Dongjin river were examined on the physico-chemical properties and phosphorus fractionations. The content of total-P in sediment of Mankyung river ranged from 290.1 to 405.4 mg/kg (average = 363.4 mg/kg), while that in sediment of Dongjin river ranged from 304.1 to 431.7 mg/kg (average = 353.6 mg/kg). In both rivers, the total-P was highest in June to September. It is presumed that surficial sediment in arable land flowed into the rivers with rainfall-runoff. Phosphorus fractionations in Mankyung and Dongjin river were apatite-P 52.1% and 42.7%, residual-P 27.3% and 34.2%, nonapatite inorganic-P 18.1% and 22.5%, and adsorbed-P 0.6% and 0.6%, respectively. Adsorbed-P in sediment was the most scarcity fraction. It thus appears that adsorbed phosphorus was not effected in aquatic ecosystem. But nonapatite inorganic-P would be highly released under changes of redox condition and pH in aquatic ecosystem.

만경강과 동진강 하천토사의 이화학전 특성과 형태별 인 함량을 조사한 결과 하천토사의 총인 함량은 만경강에서 $290.1{\sim}405.4mg/kg$ 수준으로 평균 363.4 mg/kg을, 동진강에서는 $304.1{\sim}431.7mg/kg$ 수준으로 평균 353.6 mg/kg을 나타냈고 조사지점 모두 6월과 3월에 높은 농도를 나타내었다. 이는 높은 농도의 질소와 인을 함유하고 있는 농경지 표토층이 강우-유출에 의해 하천에 유입되어 영향을 받았기 때문인 것으로 추정된다. 하천토사 내 인의 형태별 함량을 조사한 결과 만경강과 동진강에서 각 각 인회석태 인 52.1%와 42.7%, 유기태 인 27.3%와 34.2%, 비인회석태 인 18.1%와 22.5% 그리고 흡착태 인은 두 지역 모두 0.6%를 나타내었다. 하천토사 중 흡착내 인은 그 양이 매우 적어 수중생태계에 끼치는 영향이 미미할 것으로 판단되나, 비인회석태 인은 혐기성 상태가 되거나 pH가 높아지면 용출이 일어날 것으로 사료되어 관리가 필요할 것으로 나타났다.

Keywords

References

  1. Jun, S. H. (1990) Forms and mobility of pollutants retained in the sediments from the Han river, The Korean Soc. Lim. 23(1), 31-42
  2. Williams, J. D. H., Jaquet, J. M., and Thomas, R. L. (1976) Forms of phosphorus in the surficial sediments of lake Erie, J. Fish. Res. Board Can. 33, 413-429 https://doi.org/10.1139/f76-063
  3. Hieltjes, A. H. M. and Lijklerna, L. (1980) Fractionation of inorganic phosphates in calcareous sediments, J. Environ. Qual. 9(3), 405-407 https://doi.org/10.2134/jeq1980.00472425000900030015x
  4. Jun, S. H. and Park, Y. A. (1989) Forms and mobility of sediment phosphorus in lake Soyang, The Korean Soc. Lim. 22(3), 261-271
  5. Yun, S. G., Lee, J. S., Jung, G. B., Kim, M. K., Kim, S. J., Koh, M. H., and Eam, K. C. (2002) Evaluation of water characteristics on tributaries of Mankyeong river watershed, Korean J. Environ. Agric. 21(4), 237-242 https://doi.org/10.5338/KJEA.2002.21.4.237
  6. Yun, S. G., Kim, W. I., Kim, J. H., Kim, S. J., Koh, M. H., and Eom, K. C. (2002) Evaluation of water characteristics on tributaries of Mankyeong river watershed, Korean J. Environ. Agric. 21(4), 243-247 https://doi.org/10.5338/KJEA.2002.21.4.243
  7. Lee, J. S., Ihm, B. S., Kim, H. S., Cho, D. S., and Lee, S. H. (1998) Studies on the distribution of hydrophytes in relation to water system character of Mankyung river, http://apollo.mokpo.ac.kr/~planteco/frame1.html
  8. Lee, J. S., Jung, G. B., Kim, J. H., Yun, S. G., Kim, W. I., and Shin, J. D. (2004) Evaluation of water quality with BOD at Mankyeong and Dongjin river basins, Korean J. Environ. Agric. 23(2), 81-84 https://doi.org/10.5338/KJEA.2004.23.2.081
  9. Jackson, M. L. (1967) Soil chemical analysis, PreticeHall of India Private Ltd., New Delhi, India
  10. Hakanson, L. and Jansson, M. (1983) Principles of lake sedimentology, Spriinger-Verlag, Berlin, p.316
  11. Koch, M.S., Benz, R. E., and Rudnick, D. T. (2001) Solid-phase phosphorus pools in highly organic carbonate sediments of northeastern Florida Bay, Estuar. Coast. Shelf Sci. 52(2), 279-291 https://doi.org/10.1006/ecss.2000.0751
  12. Paek, S. B., Moon, B. H., and Seo, G. T. (1998) Characteristic of distribution on speciation of phosphorus in the sediment of Junam reservoir, Chanwon National University Environmental Research Institute Collected Papers. 7, 187-192
  13. Gonsiorczyk, T., Casper, P., and Koschel, R. (1998) Phosphorus binding forms in the sediment of an oligotrophic and an eutrophic hardwater lake of the Baltic distrit (Germany), Water Sci. Technol. 37(3), 51-58
  14. Kim, L. H., Choi E., and K. Stenstrom, M. (2003) Sediment characteristics, phosphorus types and phosphorus release rates between river and lake sediments, Chemosphere 50(1), 53-61 https://doi.org/10.1016/S0045-6535(02)00310-7
  15. Bostrom, B., Jansson, M., and Forsberg, C. (1982) Phosphorus release from lake sediments, Arch. Hydoriol. Beih. 18, Ergebn. Limnol., p.5-59
  16. Lee, C. W., Kown, Y. T., Park, D. K., and Kim, B. J. (1995) Phosphorus fractionation and metals speciation in the sediments of southern coastal area of Korea, J. Korean Soc. Environ. Eng. 17(7), 661-674
  17. Eckert, W., Nishri, A., and Parparova, R. (1997) Factors regulating the flux of phosphate at the sediment-water interface of a subtropical calcareous lake: a simulation study with intact sediment cores, Water Air Soil Pollut. 99, 401-409
  18. Bae, J. O. (1991) A study on forms and release rate of phosphorus in Daecheong lake sediments, Thesis of Master, Seoul National University, Seoul
  19. Golterman, H. L. (1988) Reflection on fractionation and bioabailability of sediment bound phosphate, Arch. Hydoriol. Beih. 30, Ergebn. Limnol., p.1-4
  20. Willams, J. D. H., Shear, H., and Thomas, R. L. (1980) Avalability to Senedesmus quadricauda of different forms of phosphorus in sedimentary material from the Great Lakes. Limnol. Oceanogr. 25(1), 1-11 https://doi.org/10.4319/lo.1980.25.1.0001

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