Journal of Food Hygiene and Safety (한국식품위생안전성학회지)

The Korean Society of Food Hygiene and Safety (한국식품위생안전성학회)
권호 표지

Simultaneous Determination of Simetryn and Buprofezin by Gas Chromatography with Nitrogen Fhosphorus Detector

GC-NPD를 이용한 Simetryn과 Buprofezin의 동시 분석법 연구

  • Kim Eunjeung (Seoul Metroplitan City Instutitute of Health & Environment) ;
  • Kim Sungdan (Seoul Metroplitan City Instutitute of Health & Environment) ;
  • Lee Jaekyoo (Seoul Metroplitan City Instutitute of Health & Environment) ;
  • Kim Soojin (Seoul Metroplitan City Instutitute of Health & Environment) ;
  • Lee Sangmi (Seoul Metroplitan City Instutitute of Health & Environment) ;
  • Han Sunhee (Seoul Metroplitan City Instutitute of Health & Environment) ;
  • Kang Heegon (Seoul Metroplitan City Instutitute of Health & Environment)
  • 김은정 (서울보건환경연구원 강북농수산물검사소 농산물검사팀) ;
  • 김성단 (서울보건환경연구원 강북농수산물검사소 농산물검사팀) ;
  • 이재규 (서울보건환경연구원 강북농수산물검사소 농산물검사팀) ;
  • 김수진 (서울보건환경연구원 강북농수산물검사소 농산물검사팀) ;
  • 이상미 (서울보건환경연구원 강북농수산물검사소 농산물검사팀) ;
  • 한선희 (서울보건환경연구원 강북농수산물검사소 농산물검사팀) ;
  • 강희곤 (서울보건환경연구원 강북농수산물검사소 농산물검사팀)
  • Published : 2005.09.01
Download PDF
⟨ Previous Next ⟩

Abstract

This method was described for the simultaneous determination of simetryn and buprofezin in rice, vegetables, and fruits by gas chromatography(GC) with nitrogen phosphorus detector. The GC method of simetryn and buprofezin was shown to give a linear detection ranges between $0.019\sim9.306mg/kg,\;0.023\sim11.27mg/kg$, respectively. For evaluation of GC method, simetryn spiked into rice, vegetables and fruits at the level of 4.653mg/kg was determined. The recoveries of simetryn by GC method were ranged from 57.9 to $115.9\%$. For evaluation of GC method, buprofezin spiked into rice, vegetables and fruits at the level of 2.817mg/kg was determined. The recoveries of buprofezin by GC method were ranged from 56.5 to $121.5\%.$

곡류1종(쌀), 채소류 7종(시금치, 갓, 배추, 파프리카, 고추, 오이, 토마토)와 과일류 3종(감, 사과, 키위)에서의 simetryn 과 buprofezin을 CC-NPD와 CC-MSD로 분석한 결과 다음과 같은 결론을 얻었다. 1. Simetryn을 CC-NPD로 분석한 결과 검출한계는 0.019mg/kg였으며 buprofezin을 GC-WPD로 분석한 결과 검출한계는 0.023mg/kg로 측정되었다. 2.곡류 1종, 채소류 7종, 과일류 3종 등 총 11종의 농산물에 표준용액을 첨가하여 회수 실험을 수행한 결과 곡류인 쌀에서 simetryn은 $112.5\%$, buprofezin은 $115.8\%4로 양호한 결과를 나타내었으며 채소류에서의 회수율은 simetryn이 $83.9\sim115.9\%$, buprofezin은 92.6\sim121.5\%$, 과일류에서의 회수율은 simetryn이 $57.0\sim95.9\%$, buprofezin은 $56.5\sim102\%$를 나타내었다 3. 농산물에 사용되고 있는 농약은 종류가 매우 다양하기 때문에 단일농약 성분을 검출하는 방법보다는 여러 농약 성분을 동시에 분석하는 방법이 농산물의 안전성 확보를 위해 더욱 실용적이다 식품공전상 simetryn과 buprofezin은 단성분 분석법에 따르도록 되어 있으나 본 연구를 통하여 동시분석법으로의 적용이 가능한 것을 확인하였으며, 따라서 보다 효율적인 검사가 가능할 것으로 기대된다.

Keywords

References

  1. Tomlin : The pesticide manual, 10th Ed. British Crop Protection Council, (1995)
  2. Marion, G., Dieter, M., Bernd, M.G., Thomas, W., Aiqian, Z., Xie, Q., Cheng, S., Jingwen, C., Bernhard, P., Ernst, L. and Antonius, K.: Triazines in the aquatic systems of the Eastern Chinese Rivers Liao-He and Yangtse. Chemosphere, 47, 455- 466 (2002) https://doi.org/10.1016/S0045-6535(01)00320-4
  3. Seiichi, N. and Toshio, I.: Pesticide residues in water and an aquatic plant, nelumbo nucifera, in a river mouth at lake kasumigaura, Japan. Chemoshere, 33(7), 1409-1416 (1996) https://doi.org/10.1016/0045-6535(96)00258-5
  4. Frias, S., Sanchez, M.J. and Rodriguez, M.A.: Determination of triazine compounds in ground water samples by micellar electrokinetic capillary chromatography. Analytica Chimica Acta, 503, 271-278 (2004) https://doi.org/10.1016/j.aca.2003.10.033
  5. Akiko, T., Hideko, M., Kuniaki, K. and Masaski, S.: Monitoring of herbicides in river water by gas chromatography-mass spectrometry and solid-phase extraction. J. Chromatogra. A, 754, 159-168 (1996) https://doi.org/10.1016/S0021-9673(96)00221-X
  6. Hideo, O., Mingyu, P., Isao, A., Miki, S., Takuya, O. and Masahisa, N.: Algal growth inhibition by river water pollutants in the agricultural area around Lake Biwa, Japan. Environ. pullution, 117, 411-419 (2002) https://doi.org/10.1016/S0269-7491(01)00196-8
  7. Ralf, E. and Janusz, P.: Design of automated solid-phase microextraction for trace analysis of orgainc compounds in aqueous samples. J. Chromatogra. A, 776, 293-303 (1997) https://doi.org/10.1016/S0021-9673(97)00332-4
  8. Masahiro, O., Kazuhiko, A., Hirotaka, O. and Shinjiro, H.: Determination of triazine herbicides in foods with liquid chromatography mass spectrometry. Analyst, 125, 1966-1969 (2000) https://doi.org/10.1039/b007155m
  9. Kazuhiro, H.: Application for Rapid and simultaneous Determination Method on Analysis of Simetryn, Triazophos, Pyraflufen-ethyl and Pyrimethanil in Brown Rice, Wheat and Bean. 福岡市保健環境硏究所, 27, 140-143 (2002)
  10. Sergio, A., Guillermo, Q., Javier, M., Salvador, G. and Miguel, G.: Fourier transform infrared spectrometric strategies for the determination of Buprofezin in pesticide formulations. Analytica Chimica Acta, 468, 81-90 (2002) https://doi.org/10.1016/S0003-2670(02)00656-6
  11. Pylypiw, H.M.: Rapid gas chromatographic method for the multiresidue screening of fruits and vegetables for organochlorine and organophosphate pesticides. J. AOAC International, 76, 1369-1373 (1993)
  12. Obana, H. and Hori, S.: Latest analytical methods for the residual pesticides in foods. Jpn. J. Toxicol. Environ. Health, 42, 1-16 (1996) https://doi.org/10.1248/jhs1956.42.1
  13. Lee, S.M., Papathakis, M.L., feng, H.C., Hunter, G.F. and Carr, J.E.: Multipesticide residue method for fruits and vegetables : Califormia Department of Food and Agriculture. Fresenius J. Anal. Chem., 376-383 (1991)
  14. KFDA. Food Code. Korea Food and Drug Administration, Seoul, Korea. (2003)
  15. Antonio, V.G., Gonzalez, P.E., and Aguilera, R.A.: Analysis of Buprofezin Residues in Vegetables. Application to the Degradation Study on Eggplant Grown in a Greenhouse. J. Agric. Food Chem., 41, 2319-2323, (1993) https://doi.org/10.1021/jf00036a019
  16. Antonio, V.G. and Amadeo, R.F.A.: Analysis of Buprofezin Residues in Vegetable Crops by Gas Chromatography with Mass Selective Detection in Selected Ion Monitoring Mode. J. AOAC International, 77(4), 1041-1046, (1994)
  17. Ibrahim, M.S., Magboul, K.M.A. and Kamal, M.M.: Voltammetric determination of the insecticide buprofezin in soil and water. Analytica Chimica Acta., 432, 21-26, (2001) https://doi.org/10.1016/S0003-2670(00)01352-0
  18. Hideo, N., Massao, S., Takashi, S. and Matazaemon, U.: Simple Cleanup Procedure for Analysis of Buprofezin Residues and Its Metabolite in Crops by Gas Chromatography. J. AOAC International, 77(6), 1631-1633, (1994)