An Electrochemical Evaluation on the Corrosion Resistance of Heavy Anticorrosive Paint

중방식도료의 내식성에 관한 전기화학적 평가

  • 성호진 (주영산업(주)) ;
  • 김진경 (한국해양수산연수원) ;
  • 이명훈 (한국해양대학교 기관시스템공학부) ;
  • 김기준 (한국해양대학교 기관시스템공학부) ;
  • 문경만 (한국해양대학교 기계소재공학부)
  • Published : 2005.07.01

Abstract

An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint(DFT:25um) was carried out for 5 kinds of heavy anticorrosive paints such as high solid epoxy(HE), solvent free epoxy(SE). tar epoxy(TE), phenol epoxy(PE). and ceramic epoxy(CE). Corrosion current densities obtained by Tafel extrapolation method from anodic and cathodic polarization curves didn't correspond with the values obtained by AC impedance measurement, however, the values of polarization resistance obtained from the cyclic voltammogram showed a good tendency corresponding well with the values of AC impedance measurement. Futhermore there was a good correlation against the corrosion resistance evaluation between passivity current density of the anodic polarization curve and diffusion limiting current density of the cathodic polarization curve. And corrosion resistance increased with corrosion potential shifting to noble direction. From the results discussed above. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paints.

Keywords

References

  1. H. H. Uhlig and R. W. Revie, Corrosion and Corrosion Control, 3rd ed., Wiley- Interscience, 1985
  2. F. W. Fink and W. K. Boyd, 'Corrosion of Metals in Marine Environment', MCIC Report No. 78-37, Metals and Ceramics Information Center, Battelle Columbus Laboratory, 1978
  3. M. Schumacher, Sea water Corrosion Hand Book, Noyes Data Corporation, 1979
  4. H. England and R. Heidersbach, 'The Effects of Water Depth on Cathodic Protection of Steel in Sea Water', Papers 4154, Presented at the Offshore Technology Conference, Houston, TX, 1976
  5. D. Boening, 'Offshore Cathodic Protection Experience and Economic Reassessment', Paper 2702, Presented at the Offshore Technology Conference, Houston, TX, 1976
  6. 腐蝕損失調査報告書, 日本房蝕技術協會, 1977
  7. 奧田聰: プラスチックによる防蝕技術, 日刊工業新聞社, 1982
  8. 田中丈之: 塗裝技術, No. 8, pp. 114, 1983
  9. 長倉捻: 塗裝技術, No. 10, pp. 85, 1976
  10. Pauling, L. The nature of the chemical Bond, Third Edition, Cornell University, 1960
  11. Pimantel, G, sprately, R.D.,(千葉秀詔, 大西俊一繹), 化學結合, 東京化學同人, 1977
  12. Singlaton W. T. JR., Materials Protection & Performance 9, No. 11. pp. 37, 1970
  13. 大石不二夫: プラスチックの耐久性 工業新聞社. pp. 57, 1975
  14. 奧田聰: プラスチックによる防蝕技術, 日刊工業新聞社, 1975
  15. 大石不二夫: プラスチックによる耐久性 工業新聞社, 1975
  16. 奧田聰: プラスチックによる防蝕技術, 工業新聞社, 1982
  17. 大石不二夫: プラスチックによる耐久性 工業調査會, 1975
  18. 植木憲二, 塗裝物性入門, 理工出版社, 1972
  19. 日本鋼構造協會指針, 鋼橋塗膜調査, JSSC, 18. No. 195, pp. 43, 1982
  20. 佐藤弘三: 塗裝工學, Vol. 16, No. 10. pp. 372 1981
  21. 佐藤忠明: 金屬表面技術, Vol. 37, No. 9. pp. 423 1986