Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Self-Assembly of Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH4)(C2H10N2)5.5[Cu(C2H8N2)2]3[V2P2BO12]6·17H2O and (NH4)(C2H10N2)3.5[Cu(C2H8N2)2]5[V2P2BO12]6·18H2O

  • Jung, Kyung-Na (Department of Chemistry and Research Center for Organic Display, Konkuk University) ;
  • Cho, Yoon-Suk (Department of Chemistry and Research Center for Organic Display, Konkuk University) ;
  • Yun, Ho-Seop (Department of Chemistry, Ajou University) ;
  • Do, Jung-Hwan (Department of Chemistry and Research Center for Organic Display, Konkuk University)
  • Published : 2005.08.20
Download PDF
⟨ Previous Next ⟩

Abstract

Two new copper vanadium borophosphate compounds, $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{\cdot}17H_2O,\;Cu-VBPO1\;and\;(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{\cdot}18H_2O$, Cu-VBPO2 have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, thermogravimetric analysis, IR spectroscopy, and elemental analysis. The structure of Cu-VBPO1 contains a layer anion, {$[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6$}$^{12-}$, whereas Cu-VBPO2 has an open framework anion, {$[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6$}$^{8-}$. Crystal Data: $(NH_4)(C_2H_{10}N_2)_{5.5}[Cu(C_2H_8N_2)_2]_3[V_2P_2BO_{12}]_6{\cdot}17H_2O$, monoclinic, space group I2/m (no. 12), $\alpha$ = 15.809(1) $\AA$, b = 31.107(2) $\AA$, c = 12.9343(8) $\AA$, $\beta$ = 104.325(1)$^{\circ}$, Z = 2; $(NH_4)(C_2H_{10}N_2)_{3.5}[Cu(C_2H_8N_2)_2]_5[V_2P_2BO_{12}]_6{\cdot}18H_2O$, tetragonal, space group $P4_2$/mnm (no.136), $\alpha$ = 26.832(1) $\AA$, c = 18.021(1) $\AA$, Z = 4.

Keywords

References

  1. Abrahams, B. F.; Hoskins, B. F.; Michail, D. M.; Robson, R. Nature 1994, 369, 727 https://doi.org/10.1038/369727a0
  2. Copp, S. B.; Subramanain, S.; Zaworotko Angew. Chem. Int. Ed. 1993, 32, 706
  3. Gardner, G. B.; Venkataraman, D.; Moore, J. S.; Lee, S. Nature 1995, 374, 792 https://doi.org/10.1038/374792a0
  4. Lu, J.; Harrison, W. T. A.; Jacobson, A. J. Angew. Chem. 1995, 107, 2759 https://doi.org/10.1002/ange.19951072231
  5. Yaghi, O. M.; Li, H.; Groy, T. L. J. Am. Chem. Soc. 1996, 118, 9096 https://doi.org/10.1021/ja960746q
  6. Pan, L.; Noll, B. C.; Wang, X. Chem. Commun. 1999, 157
  7. Shores, M. P.; Beauvais, L. G.; Long, J. R. Inorg. Chem. 1999, 38, 1648 https://doi.org/10.1021/ic9900408
  8. Niu, T.; Wang, X.; Jacobson, A. J. Angew. Chem. Int. Ed. 1999, 38, 1934 https://doi.org/10.1002/(SICI)1521-3773(19990712)38:13/14<1934::AID-ANIE1934>3.0.CO;2-N
  9. Bontchev, R.; Do, J.; Jacobson, A. J. Angew. Chem. Int. Ed. Engl. 1999, 38, 1937 https://doi.org/10.1002/(SICI)1521-3773(19990712)38:13/14<1937::AID-ANIE1937>3.0.CO;2-5
  10. Do, J.; Zheng, L.; Bontchev, R.; Jacobson, A. J. Solid State Sciences 2000, 2, 343 https://doi.org/10.1016/S1293-2558(00)00137-0
  11. Do, J.; Bontchev, R.; Jacobson, A. J. Inorg. Chem. 2000, 39, 4305 https://doi.org/10.1021/ic000435n
  12. Yun, H.; Do, J. Bull. Korean Chem. Soc. 2005, 26, 146 https://doi.org/10.5012/bkcs.2005.26.1.146
  13. SAINT, Version 4.05; Siemens Analytical X-ray Instruments: Madison, WI, 1995
  14. Sheldrick, G. M. Program SADABS; University of Gottingen, 1995
  15. Sheldrick, G. M. SHELXTL, Version 5.03; Siemens Analytical Xray Instruments: Madison, WI, 1995
  16. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; John Wiley and Sons: New York, 1997

Cited by

  1. A Novel Coordination Polymer Based on Decavanadate Units Linked by Copper(II) Ethylenediamine Complexes vol.304, pp.1, 2011, https://doi.org/10.1002/masy.201150611
  2. Syntheses and Structures of Two Reduced Open-framework Titanophosphates vol.29, pp.4, 2005, https://doi.org/10.5012/bkcs.2008.29.4.805
  3. Synthesis, characterization, electrochemical investigation and antioxidant activities of a new hybrid cyclohexaphosphate: Cu1.5Li(C2H10N2)P6O vol.1144, pp.None, 2005, https://doi.org/10.1016/j.molstruc.2017.05.071
  4. The origin of the electronic transitions of mixed valence polyoxovanadoborates [V12B18O60]: from an experimental to a theoretical understanding vol.43, pp.45, 2005, https://doi.org/10.1039/c9nj02549a