Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Insertion of Alkali Metals into Open Framework, TaPS6 by Using Alkali Metal Halide Fluxes: Single Crystal Structures of K0.18TaPS6, K0.28TaPS6, and Rb0.09TaPS6

  • Do, Jung-Hwan (Department of Chemistry and Research Center for Organic Display, Konkuk University) ;
  • Dong, Yong-Kwan (Department of Molecular Science and Technology, Ajou University) ;
  • Kim, Jung-Wook (Samsung Electronics Co.) ;
  • Hahn, Song-I (Department of Molecular Science and Technology, Ajou University) ;
  • Yun, Ho-Seop (Department of Molecular Science and Technology, Ajou University)
  • Published : 2005.08.20
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Abstract

Three new quaternary tantalum thiophosphates, $K_{0.18}TaPS_6,\;K_{0.28}TaPS_6,\;and\;Rb_{0.09}TaPS_6$ have been synthesized by using reactive alkali metal halide fluxes and structurally characterized by single crystal X-ray diffraction techniques. The crystal structures of $K_{0.18}TaPS_6,\;K_{0.28}TaPS_6,\;and\;Rb_{0.09}TaPS_6$ contain 3-dimensional open framework anions, $[TaPS_6]^{x-}$(x = 0.09, 0.18, 0.28) with the empty channel which disordered alkali metal cations, $K^+\;and\;Rb^+$ are located in. Crystal data: $K_{0.18}TaPS_6$, tetragonal, space group$I4_1$/acd (no. 142), a=15.874(3) $\AA$, c=13.146(4) $\AA$, V=3312.7(12) ${\AA}^3$, K, Z=16, R1=0.0545. Crystal data: $K_{0.28}TaPS_6$, tetragonal, space group $I4_1$/acd (no. 142), a=15.880(2) $\AA$, c=13.134(3) $\AA$, V=3312.1(10) ${\AA}^3$, Z=16, R1=0.0562. Crystal data: $Rb_{0.09}TaPS_6$, tetragonal, space group I41/acd (no. 142), a=15.893(3) $\AA$, c=13.163(4) $\AA$, V=3324.7(15) ${\AA}^3$, Z=16, R1=0.0432.

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References

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