Bulletin of the Korean Chemical Society

  • 제26권5호
  • /
  • Pages.735-739
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Co-adsorption of Irreversibly Adsorbing Sb and Te on Pt(111)

  • Ku, Bon-Seong (Department of Chemistry, Chungnam National University) ;
  • Kim, Tae-Gon (Department of Chemistry, Chungnam National University) ;
  • Jung, Chang-Hoon (Department of Chemistry, Chungnam National University) ;
  • Zhao, Jisheng (Department of Chemistry, Chungnam National University) ;
  • Rhee, Choong-Kyun (Department of Chemistry, Chungnam National University)
  • 발행 : 2005.05.20
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초록

Presented is a voltammetric study of co-adsorption of irreversibly adsorbing Sb and Te on Pt(111). When a layer of Sb and Te was formed via simultaneous adsorption, the reduction peak of Te was observed at 0.30 V in the initial cathodic scan. In contrast, sequential adsorption of Sb followed by Te adsorption led to a Te reduction peak at 0.50 V in the initial scan. As the voltammetric scan was continued, in addition, the voltammogram of the simultaneously co-adsorbed layer changed, while that of the sequentially co-adsorbed layer did not. These observations are discussed in terms of formation of a homogeneously mixed layer and a layer consisting of heterogeneously separated domains of Sb and Te. Also, the difference in the adsorption strength of Sb and Te was observed.

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참고문헌

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피인용 문헌

  1. Structural evolution of irreversibly adsorbed Bi on Pt(111) under potential excursion vol.17, pp.12, 2013, https://doi.org/10.1007/s10008-013-2218-9
  2. Studies on antimony telluride thin films as buffer layer for solar cell applications vol.5, pp.3, 2013, https://doi.org/10.1063/1.4808258
  3. Surface Deformation Study of the Electrodeposited Nanostructured Bi 2 Te 3 and Sb 2 Te 3 Thin Films by Double‐Exposure Digital Holographic Interferom vol.216, pp.20, 2019, https://doi.org/10.1002/pssa.201800661