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Synthesis and Structure of a Second Polymorph of Strontium Germanium Nitride: β-Sr2GeN2

  • Park, Dong-Gon (Department of Chemistry, Sookmyung Women's University) ;
  • Gal, Zoltan A. (Baker Laboratory, Department of Chemistry, Cornell University) ;
  • DiSalvo, Francis J. (Baker Laboratory, Department of Chemistry, Cornell University)
  • Published : 2005.05.20
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Abstract

A new ternary strontium germanium nitride, ${\beta}-Sr_2GeN_2$, was obtained as single crystal from constituent elements in molten Na. It crystallizes in space group Cmca (No. 64) with a = 5.441(1) $\AA$, b = 11.377(2) $\AA$, c = 12.229(2) $\AA$, and Z = 8. Its crystal structure is closely related to that of polymorphic companion, ${\alpha}-Sr_2GeN_2$, both of which contain isolated bent anions of ${GeN_2}^{4-}$.

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